Intramolecular carboxyl-catalyzed hydrolysis of sulfonamides. 5. Salt effects on the intramolecular carboxyl-catalyzed hydrolysis of sulfonamides

1981 ◽  
Vol 46 (1) ◽  
pp. 215-217 ◽  
Author(s):  
Teun Graafland ◽  
Anthony J. Kirby ◽  
Jan B. F. N. Engberts
Keyword(s):  
Salt Effects ◽  
Hydrolysis Of

Kinetic salt effects in the hydrolysis of ethyl malonate, methyl glutarate and ethyl adipate semiesters

1986 ◽  
Vol 51 (12) ◽  
pp. 2781-2785 ◽  
Author(s):  
M. Martín Herrera ◽  
J. J. Maraver Puig ◽  
F. Sánchez Burgos
Keyword(s):  
Salt Effect ◽  
Alkaline Media ◽  
Salt Effects ◽  
Coulombic Interaction ◽  
Hydroxide Ion ◽  
Ethyl Malonate ◽  
Hydrolysis Of

A study is made on the kinetic salt effect on the reaction of hydrolysis of several charged esters in alkaline media. The results are interpreted on the basis of the coulombic interaction, the salting in of hydroxide ion and a third component depending on size of the substrate.

Salt effects on the hydrolysis of sucrose

1979 ◽  
Vol 56 (5) ◽  
pp. 352 ◽  
Author(s):  
Robert S. Dordick ◽  
George A. Clarke
Keyword(s):  
Salt Effects ◽  
Hydrolysis Of
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