Trimethylsilyl azide/triflic acid, a highly efficient electrophilic aromatic amination reagent

George A. Olah; Thomas D. Ernst

doi:10.1021/jo00266a040

Trimethylsilyl azide/triflic acid, a highly efficient electrophilic aromatic amination reagent

The Journal of Organic Chemistry ◽

10.1021/jo00266a040 ◽

1989 ◽

Vol 54 (5) ◽

pp. 1203-1204 ◽

Cited By ~ 34

Author(s):

George A. Olah ◽

Thomas D. Ernst

Keyword(s):

Triflic Acid ◽

Highly Efficient ◽

Trimethylsilyl Azide

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ChemInform Abstract: Aromatic Substitution. Part 55. Trimethylsilyl Azide/Triflic Acid, a Highly Efficient Electrophilic Aromatic Amination Reagent.

ChemInform ◽

10.1002/chin.198934122 ◽

1989 ◽

Vol 20 (34) ◽

Author(s):

G. A. OLAH ◽

T. D. ERNST

Keyword(s):

Aromatic Substitution ◽

Triflic Acid ◽

Highly Efficient ◽

Trimethylsilyl Azide

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Trimethylsilyl Azide/Triflic Acid, a Highly Efficient Electrophilic Aromatic Amination Reagent

World Scientific Series in 20th Century Chemistry - Across Conventional Lines ◽

10.1142/9789812791405_0026 ◽

2003 ◽

pp. 100-101

Author(s):

George A. Olah ◽

Thomas D. Ernst

Keyword(s):

Triflic Acid ◽

Highly Efficient ◽

Trimethylsilyl Azide

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Continuous-Flow Electrophilic Amination of Arenes and Schmidt Reaction of Carboxylic Acids Utilizing the Superacidic Trimethylsilyl Azide/Triflic Acid Reagent System

The Journal of Organic Chemistry ◽

10.1021/acs.joc.6b02085 ◽

2016 ◽

Vol 81 (19) ◽

pp. 9372-9380 ◽

Cited By ~ 7

Author(s):

Yuesu Chen ◽

Bernhard Gutmann ◽

C. Oliver Kappe

Keyword(s):

Carboxylic Acids ◽

Continuous Flow ◽

Triflic Acid ◽

Schmidt Reaction ◽

Electrophilic Amination ◽

Trimethylsilyl Azide ◽

Acid Reagent

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ChemInform Abstract: Highly Efficient One-Pot Synthesis of 2-Aminobenzoxazoles Using Triflic Acid as a Cyclodesulfurizing Reagent.

ChemInform ◽

10.1002/chin.201227127 ◽

2012 ◽

Vol 43 (27) ◽

pp. no-no

Author(s):

Gopal L. Khatik ◽

Namita Dube ◽

Anang Pal ◽

Vipin A. Nair

Keyword(s):

Triflic Acid ◽

One Pot ◽

Highly Efficient ◽

One Pot Synthesis

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Iodosylbenzene-trimethylsilyl azide-boron trifluoride etherate: A highly efficient system for direct synthesis of allyl azides from allylsilanes

Tetrahedron Letters ◽

10.1016/s0040-4039(01)91354-1 ◽

1987 ◽

Vol 28 (50) ◽

pp. 6289-6292 ◽

Cited By ~ 33

Author(s):

Masao Arimoto ◽

Hideo Yamaguchi ◽

Eiichi Fujita ◽

Masahito Ochiai ◽

Yoshimitsu Nagao

Keyword(s):

Boron Trifluoride ◽

Direct Synthesis ◽

Boron Trifluoride Etherate ◽

Efficient System ◽

Highly Efficient ◽

Trimethylsilyl Azide

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Triflic acid-catalyzed metal-free synthesis of (E)-2-cyanoacrylamides and 3-substituted azetidine-2,4-diones

New Journal of Chemistry ◽

10.1039/c7nj05169g ◽

2018 ◽

Vol 42 (8) ◽

pp. 6433-6440 ◽

Cited By ~ 5

Author(s):

Bapurao D. Rupanwar ◽

Santosh S. Chavan ◽

Anil M. Shelke ◽

Gurunath M. Suryavanshi

Keyword(s):

Biologically Active ◽

Efficient Synthesis ◽

Triflic Acid ◽

Metal Free ◽

Highly Efficient ◽

Acid Catalyzed

A TfOH-catalyzed highly efficient synthesis of biologically active (E)-2-cyanoacrylamides and 3-substituted azetidine-2,4-diones has been reported with 64–94% yields under metal-free conditions.

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ChemInform Abstract: Iodosylbenzene-Trimethylsilyl Azide-Boron Trifluoride Etherate: A Highly Efficient System for Direct Synthesis of Allyl Azides from Allylsilanes.

ChemInform ◽

10.1002/chin.198820116 ◽

1988 ◽

Vol 19 (20) ◽

Author(s):

M. ARIMOTO ◽

H. YAMAGUCHI ◽

E. FUJITA ◽

M. OCHIAI ◽

Y. NAGAO

Keyword(s):

Boron Trifluoride ◽

Direct Synthesis ◽

Boron Trifluoride Etherate ◽

Efficient System ◽

Highly Efficient ◽

Trimethylsilyl Azide

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Trimethylsilyl azide (C3H9N3Si): a highly efficient additive for tailoring fluoroethylene carbonate (FEC) based electrolytes for Li-metal batteries

Journal of Materials Chemistry A ◽

10.1039/c9ta03713f ◽

2019 ◽

Vol 7 (22) ◽

pp. 13441-13448 ◽

Cited By ~ 8

Author(s):

Seong-Jin Park ◽

Jang-Yeon Hwang ◽

Yang-Kook Sun

Keyword(s):

Cycling Stability ◽

Highly Efficient ◽

Trimethylsilyl Azide ◽

Fluoroethylene Carbonate ◽

Practical Level

The addition of trimethylsilyl azide (C3H9N3Si) to FEC-based electrolytes enhances Li-metal stability and thus it enables the outstanding cycling stability of Li-metal battery at a practical level.

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