Determination of the enantiomeric purity of chiral allyl alcohols and allyl ethers by platinum-195 NMR spectroscopy

Piero Salvadori; Gloria Uccello-Barretta; Sergio Bertozzi; Roberta Settambolo; Raffaello Lazzaroni

doi:10.1021/jo00259a029

Determination of the enantiomeric purity of chiral allyl alcohols and allyl ethers by platinum-195 NMR spectroscopy

The Journal of Organic Chemistry ◽

10.1021/jo00259a029 ◽

1988 ◽

Vol 53 (24) ◽

pp. 5768-5770 ◽

Cited By ~ 16

Author(s):

Piero Salvadori ◽

Gloria Uccello-Barretta ◽

Sergio Bertozzi ◽

Roberta Settambolo ◽

Raffaello Lazzaroni

Keyword(s):

Nmr Spectroscopy ◽

Enantiomeric Purity ◽

Allyl Ethers ◽

Allyl Alcohols

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ChemInform Abstract: Determination of the Enantiomeric Purity of Chiral Allyl Alcohols and Allyl Ethers by 195Pt NMR Spectroscopy.

ChemInform ◽

10.1002/chin.198920322 ◽

1989 ◽

Vol 20 (20) ◽

Author(s):

P. SALVADORI ◽

G. UCCELLO-BARRETTA ◽

S. BERTOZZI ◽

R. SETTAMBOLO ◽

R. LAZZARONI

Keyword(s):

Nmr Spectroscopy ◽

Enantiomeric Purity ◽

Allyl Ethers ◽

Allyl Alcohols

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Use of shift reagent with MTPA derivatives in 1H NMR spectroscopy. III. Determination of absolute configuration and enantiomeric purity of primary carbinols with chiral center at the C-2 position

Tetrahedron Letters ◽

10.1016/s0040-4039(01)83433-x ◽

1977 ◽

Vol 18 (47) ◽

pp. 4085-4088 ◽

Cited By ~ 21

Author(s):

Fujiko Yasuhara ◽

Shozo Yamaguchi

Keyword(s):

Nmr Spectroscopy ◽

1H Nmr ◽

Absolute Configuration ◽

1H Nmr Spectroscopy ◽

Shift Reagent ◽

Enantiomeric Purity ◽

Chiral Center ◽

Determination Of Absolute Configuration

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Determination of Enantiomeric Purity for Chiral π‐Basic Aromatic Alcohols Chiral Samples by 1 H NMR Spectroscopy

Bulletin of the Korean Chemical Society ◽

10.1002/bkcs.11906 ◽

2019 ◽

Vol 41 (1) ◽

pp. 4-9 ◽

Cited By ~ 1

Author(s):

Kyu Sung Heo ◽

Jae Jeong Ryoo

Keyword(s):

Nmr Spectroscopy ◽

Enantiomeric Purity ◽

H Nmr ◽

Aromatic Alcohols

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ChemInform Abstract: First Principles Design of Derivatizing Agent for Direct Determination of Enantiomeric Purity of Chiral Alcohols and Amines by NMR Spectroscopy.

ChemInform ◽

10.1002/chin.201038196 ◽

2010 ◽

Vol 41 (38) ◽

pp. no-no

Author(s):

Nikolay V. Orlov ◽

Valentine P. Ananikov

Keyword(s):

Nmr Spectroscopy ◽

First Principles ◽

Direct Determination ◽

Enantiomeric Purity ◽

Chiral Alcohols ◽

Derivatizing Agent

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P*-Chiral phosphapalladacycle as derivatizing agent for enantiomeric purity determination of α-amino acids by means of 31P NMR spectroscopy

Tetrahedron Asymmetry ◽

10.1016/s0957-4166(00)00221-4 ◽

2000 ◽

Vol 11 (14) ◽

pp. 2907-2916 ◽

Cited By ~ 29

Author(s):

Valery V. Dunina ◽

Ol'ga N. Gorunova ◽

Michail V. Livantsov ◽

Yuri K. Grishin

Keyword(s):

Amino Acids ◽

Nmr Spectroscopy ◽

31P Nmr ◽

Enantiomeric Purity ◽

31P Nmr Spectroscopy ◽

Purity Determination ◽

Derivatizing Agent

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Use of shift reagent with mtpa derivatives in 19F NMR spectroscopy: III. Determination of absolute configuration and enantiomeric purity of secondary alcohols

Bulletin des Sociétés Chimiques Belges ◽

10.1002/bscb.19780870707 ◽

2010 ◽

Vol 87 (7) ◽

pp. 545-552 ◽

Cited By ~ 8

Author(s):

A. J. De Van Wal ◽

E. M. Merckx ◽

G. L. Lemière ◽

T. A. van Osselaer ◽

J. A. Lepoivre ◽

...

Keyword(s):

Nmr Spectroscopy ◽

Absolute Configuration ◽

Shift Reagent ◽

Enantiomeric Purity ◽

19F Nmr ◽

Secondary Alcohols ◽

19F Nmr Spectroscopy ◽

Determination Of Absolute Configuration

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Chemical Shift Nonequivalence of Enantiomers of Amino Acid Derivatives in 1H NMR and 19F NMR Spectroscopy Induced by L-Chirasil- Val.

Zeitschrift für Naturforschung B ◽

10.1515/znb-1992-0725 ◽

1992 ◽

Vol 47 (7) ◽

pp. 1034-1036 ◽

Cited By ~ 2

Author(s):

Bernhard Koppenhoefer ◽

Michael Hummel

Keyword(s):

Amino Acid ◽

Nmr Spectroscopy ◽

Chemical Shift ◽

Methyl Esters ◽

Enantiomeric Purity ◽

Peak Splitting ◽

H Nmr ◽

Acid Methyl ◽

Amino Acid Methyl Esters

Enantiomers of N-trifluoroacetyl-amino acid methyl esters in CC14 solution, after addition of the chiral polysiloxane (L)-Chirasil-Val, display a chemical shift nonequivalence ΔΔδ in both 1H NMR and 19F NMR spectroscopy. The effects found for the leucine and valine derivatives can be correlated with the thermodynamic parameters of interaction in the undiluted system, as determined by gas chromatography. In CDC13 solution, no peak splitting was observed. The method is potentially useful for the determination of the enantiomeric purity of substrates of low volatility.

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Isotopic Labeling for Determination of Enantiomeric Purity by2H NMR Spectroscopy

Organic Letters ◽

10.1021/ol702225r ◽

2007 ◽

Vol 9 (25) ◽

pp. 5179-5182 ◽

Cited By ~ 7

Author(s):

Hayley Jackman ◽

Stephen P. Marsden ◽

Peter Shapland ◽

Simon Barrett

Keyword(s):

Nmr Spectroscopy ◽

Isotopic Labeling ◽

Enantiomeric Purity

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Use of shift reagent with MTPA derivatives in 1H NMR spectroscopy. IV. Determination of absolute configuration and enantiomeric purity of amino acid derivatives.

Tetrahedron Letters ◽

10.1016/s0040-4039(01)95204-9 ◽

1978 ◽

Vol 19 (44) ◽

pp. 4289-4292 ◽

Cited By ~ 9

Author(s):

Fujiko Yasuhara ◽

Kuninobu Kabuto ◽

Shozo Yamaguchi

Keyword(s):

Amino Acid ◽

Nmr Spectroscopy ◽

1H Nmr ◽

Absolute Configuration ◽

1H Nmr Spectroscopy ◽

Shift Reagent ◽

Enantiomeric Purity ◽

Amino Acid Derivatives ◽

Determination Of Absolute Configuration

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First principles design of derivatizing agent for direct determination of enantiomeric purity of chiral alcohols and amines by NMR spectroscopy

Chemical Communications ◽

10.1039/b923359h ◽

2010 ◽

Vol 46 (18) ◽

pp. 3212 ◽

Cited By ~ 32

Author(s):

Nikolay V. Orlov ◽

Valentine P. Ananikov

Keyword(s):

Nmr Spectroscopy ◽

First Principles ◽

Direct Determination ◽

Enantiomeric Purity ◽

Chiral Alcohols ◽

Derivatizing Agent

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