New method for the facile reduction of .alpha.-nitro sulfones to nitroalkanes via an electron-transfer-hydrogen atom abstraction mechanism

1988 ◽  
Vol 53 (17) ◽  
pp. 3897-3900 ◽  
Author(s):  
Jian Chen ◽  
Dennis D. Tanner
Keyword(s):  
Electron Transfer ◽  
Hydrogen Atom ◽  
New Method ◽  
Hydrogen Atom Abstraction

Properties and reactivities of nonheme iron(iv)–oxo versus iron(v)–oxo: long-range electron transfer versus hydrogen atom abstraction

2014 ◽  
Vol 16 (41) ◽  
pp. 22611-22622 ◽  
Author(s):  
Baharan Karamzadeh ◽  
Devendra Singh ◽  
Wonwoo Nam ◽  
Devesh Kumar ◽  
Sam P. de Visser
Keyword(s):  
Electron Transfer ◽  
Hydrogen Atom ◽  
Long Range ◽  
Cation Radical ◽  
Nonheme Iron ◽  
Hydrogen Atom Abstraction ◽  
Computational Studies ◽  
Radical Species ◽  
Oxo Ligand

Computational studies show that the perceived nonheme iron(v)–oxo is actually an iron(iv)–oxo ligand cation radical species.

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