Transition metal-promoted reactions. Part 21. Tungsten hexacarbonyl-mediated carbon-sulfur bond cleavage reactions

1988 ◽  
Vol 53 (11) ◽  
pp. 2536-2539 ◽  
Author(s):  
Chi Tat Ng ◽  
Xiaojun Wang ◽  
Tien Yau Luh
Keyword(s):  
Transition Metal ◽  
Bond Cleavage ◽  
Tungsten Hexacarbonyl ◽  
Cleavage Reactions ◽  
Sulfur Bond

scholarly journals N–O Cleavage reactions of heterobicycloalkene-fused 2-isoxazolines

2014 ◽  
Vol 10 ◽  
pp. 2200-2205 ◽  
Author(s):  
Jaipal R Nagireddy ◽  
Geoffrey K Tranmer ◽  
Emily Carlson ◽  
William Tam
Keyword(s):  
Transition Metal ◽  
Raney Nickel ◽  
Bond Cleavage ◽  
Chromatographic Purification ◽  
Aqueous Methanol ◽  
Cleavage Reactions

Transition metal-mediated N–O bond cleavage reactions of heterobicycloalkene-fused 3-methyl-2-isoxazolines were investigated. Optimal cleavage conditions were found with Raney nickel/AlCl3 mediation in aqueous methanol. The reaction provided a diverse collection of novel heterobicycle-fused β-hydroxyketones with good to excellent yields (66–95%) and without the need for chromatographic purification.

Molybdenum-molybdenum and phosphorus-phosphorus or sulfur-sulfur bond cleavage reactions of organic substrates with compounds containing a metal-metal triple bond

1987 ◽  
Vol 6 (4) ◽  
pp. 829-833 ◽  
Author(s):  
Howard. Alper ◽  
Frederick W. B. Einstein ◽  
Frederick W. Hartstock ◽  
Richard H. Jones
Keyword(s):  
Triple Bond ◽  
Bond Cleavage ◽  
Organic Substrates ◽  
Metal Metal ◽  
Cleavage Reactions ◽  
Sulfur Bond
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