Separation of mass law and solvent effects in kinetics of solvolyses of p-nitrobenzoyl chloride in aqueous binary mixtures

1988 ◽  
Vol 53 (4) ◽  
pp. 724-728 ◽  
Author(s):  
T. William Bentley ◽  
H. Carl Harris
Keyword(s):  
Binary Mixtures ◽  
Solvent Effects ◽  
Kinetics Of ◽  
Aqueous Binary Mixtures

THE ALKALINE CLEAVAGE OF o-NITROBENZYLTRIMETHYLSILANE SOLVENT EFFECTS IN THE DIOXANE–WATER SYSTEM

1963 ◽  
Vol 41 (6) ◽  
pp. 1525-1530 ◽  
Author(s):  
H. R. Allcock
Keyword(s):  
Transition State ◽  
Solvent Effects ◽  
Water System ◽  
Solvent Polarity ◽  
High Water ◽  
Aqueous Dioxane ◽  
Alkaline Cleavage ◽  
Rate Of Reaction ◽  
Kinetics Of

The kinetics of alkaline cleavage of o-nitrobenzyltrimethylsilane were examined in aqueous dioxane media. At high water concentrations, increases in solvent polarity retard the cleavage, as required by a mechanism involving charge dispersion in the transition state. At high dioxane concentrations, solvent polarity increases are accompanied by increases in the rate of reaction, a result which may reflect association between the solvent components.

Kinetics of lipase-catalyzed esterification in organic media: Correct model and solvent effects on parameters

1999 ◽  
Vol 24 (8-9) ◽  
pp. 463-470 ◽  
Author(s):  
Anja E.M. Janssen ◽  
Birte J. Sjursnes ◽  
Alexander V. Vakurov ◽  
Peter J. Halling
Keyword(s):  
Solvent Effects ◽  
Organic Media ◽  
Correct Model ◽  
Kinetics Of

The solvent effects on the kinetics of bacterial formate dehydrogenase reaction

1990 ◽  
Vol 1039 (3) ◽  
pp. 290-296 ◽  
Author(s):  
Alexander P. Demchenko ◽  
Oksana I. Rusyn ◽  
Alexey M. Egorov ◽  
Vladimir I. Tishkov
Keyword(s):  
Solvent Effects ◽  
Formate Dehydrogenase ◽  
Dehydrogenase Reaction ◽  
Kinetics Of

scholarly journals Crystallization Kinetics of Binary Mixtures of Polyoxymethylene and Novolak Resin.

1991 ◽  
Vol 48 (12) ◽  
pp. 771-774 ◽  
Author(s):  
Xiuxun WANG ◽  
Hiromu SAITO ◽  
Takashi INOUE
Keyword(s):  
Binary Mixtures ◽  
Crystallization Kinetics ◽  
Kinetics Of
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