Kinetic and product hydrogen-deuterium isotope effects in ene reactions: a model for understanding apparently anomalous effects

Zhiguo Song; Douglas R. Chrisope; Peter Beak

doi:10.1021/jo00226a046

Kinetic and product hydrogen-deuterium isotope effects in ene reactions: a model for understanding apparently anomalous effects

The Journal of Organic Chemistry ◽

10.1021/jo00226a046 ◽

1987 ◽

Vol 52 (17) ◽

pp. 3938-3940 ◽

Cited By ~ 9

Author(s):

Zhiguo Song ◽

Douglas R. Chrisope ◽

Peter Beak

Keyword(s):

Isotope Effects ◽

Ene Reactions ◽

Hydrogen Deuterium ◽

Deuterium Isotope Effects

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ChemInform Abstract: Kinetic and Product Hydrogen-Deuterium Isotope Effects in Ene Reactions: A Model for Understanding Apparently Anomalous Effects.

ChemInform ◽

10.1002/chin.198807073 ◽

1988 ◽

Vol 19 (7) ◽

Author(s):

Z. SONG ◽

D. R. CHRISOPE ◽

P. BEAK

Keyword(s):

Isotope Effects ◽

Ene Reactions ◽

Hydrogen Deuterium ◽

Deuterium Isotope Effects

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ChemInform Abstract: Investigation of the Mechanisms of Ene Reactions of Carbonyl Enophiles by Intermolecular and Intramolecular Hydrogen-Deuterium Isotope Effects: Partitioning of Reaction Intermediates.

ChemInform ◽

10.1002/chin.199106063 ◽

2010 ◽

Vol 22 (6) ◽

pp. no-no

Author(s):

Z. SONG ◽

P. BEAK

Keyword(s):

Isotope Effects ◽

Reaction Intermediates ◽

Ene Reactions ◽

Hydrogen Deuterium ◽

Deuterium Isotope Effects ◽

Intramolecular Hydrogen

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Investigation of the mechanisms of ene reactions of carbonyl enophiles by intermolecular and intramolecular hydrogen-deuterium isotope effects: partitioning of reaction intermediates

Journal of the American Chemical Society ◽

10.1021/ja00178a042 ◽

1990 ◽

Vol 112 (22) ◽

pp. 8126-8134 ◽

Cited By ~ 31

Author(s):

Zhiguo Song ◽

Peter Beak

Keyword(s):

Isotope Effects ◽

Reaction Intermediates ◽

Ene Reactions ◽

Hydrogen Deuterium ◽

Deuterium Isotope Effects ◽

Intramolecular Hydrogen

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Hydrogen/Deuterium-Isotope Effects on NMR Chemical Shifts and Symmetry of Homoconjugated Hydrogen-Bonded Ions in Polar Solution

Journal of the American Chemical Society ◽

10.1021/ja0017615 ◽

2000 ◽

Vol 122 (51) ◽

pp. 12878-12879 ◽

Cited By ~ 67

Author(s):

Parwin Schah-Mohammedi ◽

Ilja G. Shenderovich ◽

Carsten Detering ◽

Hans-Heinrich Limbach ◽

Peter M. Tolstoy ◽

...

Keyword(s):

Chemical Shifts ◽

Isotope Effects ◽

Polar Solution ◽

Nmr Chemical Shifts ◽

Hydrogen Deuterium ◽

Deuterium Isotope Effects ◽

Hydrogen Bonded

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Hydrogen/deuterium isotope effects in water radiolysis. 1. The mechanism of chemically induced dynamic electron polarization generation in spurs

The Journal of Physical Chemistry ◽

10.1021/j100343a039 ◽

1989 ◽

Vol 93 (6) ◽

pp. 2412-2421 ◽

Cited By ~ 27

Author(s):

D. M. Bartels ◽

M. T. Craw ◽

Ping Han ◽

A. D. Trifunac

Keyword(s):

Isotope Effects ◽

Water Radiolysis ◽

Electron Polarization ◽

Chemically Induced ◽

Hydrogen Deuterium ◽

Deuterium Isotope Effects

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Hydrogen/deuterium isotope effects in water radiolysis. 4. The mechanism of aquated hydrogen atom .dblharw. solvated electron [ (H)aq .dblharw. (e-)aq] interconversion

The Journal of Physical Chemistry ◽

10.1021/j100191a033 ◽

1992 ◽

Vol 96 (12) ◽

pp. 4899-4906 ◽

Cited By ~ 32

Author(s):

Ping Han ◽

D. M. Bartels

Keyword(s):

Hydrogen Atom ◽

Isotope Effects ◽

Water Radiolysis ◽

Solvated Electron ◽

Hydrogen Deuterium ◽

Deuterium Isotope Effects

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Electron spin resonance studies of hydroxysemiquinone radicals. Hydrogen-deuterium isotope effects in intramolecular hydrogen bonds

Journal of the American Chemical Society ◽

10.1021/ja01044a009 ◽

1969 ◽

Vol 91 (16) ◽

pp. 4369-4380 ◽

Cited By ~ 41

Author(s):

Julien Gendell ◽

William R. Miller ◽

George K. Fraenkel

Keyword(s):

Electron Spin Resonance ◽

Hydrogen Bonds ◽

Electron Spin ◽

Isotope Effects ◽

Intramolecular Hydrogen Bonds ◽

Spin Resonance ◽

Hydrogen Deuterium ◽

Deuterium Isotope Effects ◽

Intramolecular Hydrogen

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Hydrogen-deuterium isotope effects for the base promoted E2 reaction of quaternary ammonium ions. The effect of base, solvent, and structure on the nature of the transition state.

Tetrahedron Letters ◽

10.1016/s0040-4039(01)95577-7 ◽

1973 ◽

Vol 14 (1) ◽

pp. 61-64 ◽

Cited By ~ 1

Author(s):

P.J. Smith ◽

S.K. Tsui

Keyword(s):

Transition State ◽

Quaternary Ammonium ◽

Isotope Effects ◽

Ammonium Ions ◽

Quaternary Ammonium Ions ◽

Hydrogen Deuterium ◽

Deuterium Isotope Effects

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Hydrogen/deuterium isotope effects in water radiolysis. 3. Atomic hydrogen in acidic water/water-d2 mixtures

The Journal of Physical Chemistry ◽

10.1021/j100176a061 ◽

1991 ◽

Vol 95 (23) ◽

pp. 9370-9374 ◽

Cited By ~ 3

Author(s):

Ping Han ◽

D. M. Bartels

Keyword(s):

Atomic Hydrogen ◽

Isotope Effects ◽

Water Radiolysis ◽

Acidic Water ◽

Hydrogen Deuterium ◽

Deuterium Isotope Effects

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Kinetic hydrogen-hydrogen/hydrogen-deuterium/deuterium-hydrogen/deuterium-deuterium isotope effects on nondegenerate stepwise reversible double proton transfer reactions. NMR study of the tautomerism of meso-tetraphenylchlorin

Journal of the American Chemical Society ◽

10.1021/ja00009a050 ◽

1991 ◽

Vol 113 (9) ◽

pp. 3550-3558 ◽

Cited By ~ 18

Author(s):

Martin Schlabach ◽

Gerd Scherer ◽

Hans Heinrich Limbach

Keyword(s):

Proton Transfer ◽

Isotope Effects ◽

Transfer Reactions ◽

Double Proton Transfer ◽

Nmr Study ◽

Proton Transfer Reactions ◽

Hydrogen Deuterium ◽

Deuterium Isotope Effects

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