Intramolecular reactions of azidoalkenes. The 2-(azidoalkyl)quinone rearrangement

1984 ◽  
Vol 49 (9) ◽  
pp. 1676-1678 ◽  
Author(s):  
Arthur G. Schultz ◽  
Wayne G. McMahon
Keyword(s):  
Intramolecular Reactions

scholarly journals Studies on the formation of complex oxidation and condensation products of phenols. Part III. -Rearrangements of oxidation-reduction type in the diquinone group

1933 ◽  
Vol 143 (848) ◽  
pp. 223-228 ◽  
Keyword(s):  
Hydroxyl Group ◽  
Hydrogen Atoms ◽  
Blue Colour ◽  
Highly Active ◽  
Oxidation Reduction ◽  
Intramolecular Reactions ◽  
Trimethyl Ether ◽  
Free Hydroxyl ◽  
Ethereal Oxygen ◽  
Complex Oxidation

The diquinones have been but little investigated, and as they contain two condensed highly active quinonid systems it is to be anticipated that they should be capable of interesting intramolecular reactions. When heated to 210-215º, 4 : 4'-dimethoxydiquinone is rapidly converted into a red crystalline isomeride (yield, 90%), soluble in alkali with an intense blue colour, and yielding a mono-acetate indicating the occurrence of a free hydroxyl group. Two hydrogen atoms are taken up on reduction, and the phenolic product yields a triacetate and a trimethyl ether. It follows that of the four carbonyl oxygens of 4 : 4'-dimethoxydiquinone, one has been converted into a hydroxyl group, and another which does not exhibit any functional activity, is probably present as ethereal oxygen. These results led to formula (III) as representing the product of rearrangement.

scholarly journals Pyridinesilver Tetraoxometallate Complexes: Overview of the Synthesis, Structure, and Properties of Pyridine Complexed AgXO4 (X = Cl, Mn, Re) Compounds

Inorganics ◽  
2021 ◽  
Vol 9 (11) ◽  
pp. 79
Author(s):  
Fernanda Paiva Franguelli ◽  
Kende Attila Béres ◽  
Laszló Kótai
Keyword(s):  
Organic Chemistry ◽  
Thermal Behavior ◽  
Structure And Properties ◽  
Pyridine Complexes ◽  
Intramolecular Reactions

We reviewed the synthesis, structure, and properties of pyridine complexes of AgXO4 (X = Cl, Mn, and Re) compounds with various compositions ([AgPy2] XO4, [AgPy2XO4]·0.5Py, [AgPy4] XO4, and 4 [AgPy2XO4] [AgPy4] XO4). We also clarified the controversial information about the existence and composition of pyridine complexes of silver permanganate, used widely as mild and selective oxidants in organic chemistry. We discussed in detail the available structural and spectroscopic (IR, Raman, and UV) data and thermal behavior, including the existence and consequence of quasi-intramolecular reactions between the reducing ligand and anions containing oxygen.

Intramolecular Reactions in Cyclophanes

ChemInform ◽  
2005 ◽  
Vol 36 (52) ◽  
Author(s):  
Henning Hopf
Keyword(s):  
Intramolecular Reactions

ChemInform Abstract: Intramolecular Reactions of Nitrilimines as a Fruitful Source of Heterocycles

ChemInform ◽  
2010 ◽  
Vol 29 (16) ◽  
pp. no-no
Author(s):  
G. BROGGINI ◽  
G. MOLTENI ◽  
G. ZECCHI
Keyword(s):  
Intramolecular Reactions
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