Nonlinear least-squares method of separating the second- and third-order rate constants for the ionic bromination of alkenes in carbon tetrachloride at 25.degree.C

1984 ◽  
Vol 49 (5) ◽  
pp. 761-763 ◽  
Author(s):  
George H. Schmid ◽  
Barry Toyonaga
Keyword(s):  
Carbon Tetrachloride ◽  
Least Squares ◽  
Rate Constants ◽  
Least Squares Method ◽  
Nonlinear Least Squares ◽  
Third Order ◽  
Order Rate ◽  
Nonlinear Least Squares Method ◽  
Ionic Bromination

scholarly journals MIM and nonlinear least‐squares inversions of AEM data in Barataria basin, Louisiana

Geophysics ◽  
2003 ◽  
Vol 68 (4) ◽  
pp. 1126-1131 ◽  
Author(s):  
Melissa Whitten Bryan ◽  
Kenneth W. Holladay ◽  
Clyde J. Bergeron ◽  
Juliette W. Ioup ◽  
George E. Ioup
Keyword(s):  
Least Squares ◽  
Water Depth ◽  
Least Squares Method ◽  
Nonlinear Least Squares ◽  
Image Method ◽  
Water Conductivity ◽  
Near Surface ◽  
Barataria Basin ◽  
Airborne Electromagnetic Survey ◽  
Nonlinear Least Squares Method

An airborne electromagnetic survey was performed over the marsh and estuarine waters of the Barataria basin of Louisiana. Two inversion methods were applied to the measured data to calculate layer thicknesses and conductivities: the modified image method (MIM) and a nonlinear least‐squares method of inversion using two two‐layer forward models and one three‐layer forward model, with results generally in good agreement. Uniform horizontal water layers in the near‐shore Gulf of Mexico with the fresher (less saline, less conductive) water above the saltier (more saline, more conductive) water can be seen clearly. More complex near‐surface layering showing decreasing salinity/conductivity with depth can be seen in the marshes and inland areas. The first‐layer water depth is calculated to be 1–2 m, with the second‐layer water depth around 4 m. The first‐layer marsh and beach depths are computed to be 0–3 m, and the second‐layer marsh and beach depths vary from 2 to 9 m. The first‐layer water conductivity is calculated to be 2–3 S/m, with the second‐layer water conductivity around 3 to 4 S/m and the third‐layer water conductivity 4–5 S/m. The first‐layer marsh conductivity is computed to be mainly 1–2 S/m, and the second‐ and third‐layer marsh conductivities vary from 0.5 to 1.5 S/m, with the conductivities decreasing as depth increases except on the beach, where layer three has a much higher conductivity, ranging up to 3 S/m.

The Strength Evaluation and Reliability Analysis of Periodic Symmetric Struts Support

2011 ◽  
Vol 462-463 ◽  
pp. 1164-1169
Author(s):  
Jing Xiang Yang ◽  
Ya Xin Zhang ◽  
Mamtimin Gheni ◽  
Ping Ping Chang ◽  
Kai Yin Chen ◽  
...  
Keyword(s):  
Distribution Function ◽  
Probability Distribution ◽  
Stress Distribution ◽  
Least Squares ◽  
Reliability Analysis ◽  
Least Squares Method ◽  
Nonlinear Least Squares ◽  
Distribution Model ◽  
Different Types ◽  
Nonlinear Least Squares Method

In this paper, strength evaluations and reliability analysis are conducted for different types of PSSS(Periodically Symmetric Struts Supports) based on the FEA(Finite Element Analysis). The numerical models are established at first, and the PMA(Prestressed Modal Analysis) is conducted. The nodal stress value of all of the gauss points in elements are extracted out and the stress distributions are evaluated for each type of PSSS. Then using nonlinear least squares method, curve fitting is carried out, and the stress probability distribution function is obtained. The results show that although using different number of struts, the stress distribution function obeys the exponential distribution. By using nonlinear least squares method again for the distribution parameters a and b of different exponential functions, the relationship between number of struts and distribution function is obtained, and the mathematical models of the stress probability distribution functions for different supports are established. Finally, the new stress distribution model is introduced by considering the DSSI(Damaged Stress-Strength Interference), and the reliability evaluation for different types of periodically symmetric struts supports is carried out.

A NONLINEAR LEAST‐SQUARES METHOD FOR SEISMIC REFRACTION MAPPING—PART I: ALGORITHM AND PROCEDURE

Geophysics ◽  
1972 ◽  
Vol 37 (2) ◽  
pp. 260-272 ◽  
Author(s):  
Leonidas C. Ocola
Keyword(s):  
Least Squares ◽  
Least Squares Method ◽  
Seismic Refraction ◽  
Vertical Plane ◽  
Nonlinear Least Squares ◽  
Inversion Method ◽  
Almost Everywhere ◽  
Isotropic Media ◽  
Time Term ◽  
Nonlinear Least Squares Method

An iterative inversion method (Reframap) based on the kinematic properties of critically refracted waves is developed. The method is based on ray tracing and assumes homogeneous and isotropic media and ray paths confined to a vertical plane through each source‐detector pair. Unlike the earlier Profile or Time‐Term Methods, no restrictions are imposed on interface topography except that it be continuous almost everywhere (in the mathematical sense). As in the preexisting methods, more observations than unknowns are assumed. The algorithm and procedure, on which the Reframap Method is based, generate apparent dips for each source detector pair at the noncritical interfaces from the slope of a least‐squares line approximation to the interface functional in the neighborhood of each refraction point. In turn, the dip and path along the critical refractor is, at every iteration, pairwise approximated by a line through the critical refracting points. The incidence angles are computed recursively by Snell’s law. The solution of the overdetermined, nonlinear multiple refractor time‐distance system of simultaneous equations is sought by Marquardt’s algorithm for least‐squares estimation of critical refractor velocity and vertical thickness under each element.

Analysis of photoacoustic waveforms using the nonlinear least squares method

1992 ◽  
Vol 42 (1) ◽  
pp. 29-48 ◽  
Author(s):  
Jeanne Rudzki Small ◽  
Louis J. Libertini ◽  
Enoch W. Small
Keyword(s):  
Least Squares ◽  
Least Squares Method ◽  
Nonlinear Least Squares ◽  
Nonlinear Least Squares Method

Linear least squares method in nonlinear parametric inverse problems

2020 ◽  
Vol 28 (2) ◽  
pp. 307-312
Author(s):  
Leonid L. Frumin
Keyword(s):  
Inverse Problems ◽  
Least Squares ◽  
Least Squares Method ◽  
Nonlinear Least Squares ◽  
Linear Least Squares ◽  
Estimation Of Parameters ◽  
Discrete Approximations ◽  
Operator Equations ◽  
Transcendental Functions ◽  
Nonlinear Least Squares Method

AbstractA generalization of the linear least squares method to a wide class of parametric nonlinear inverse problems is presented. The approach is based on the consideration of the operator equations, with the selected function of parameters as the solution. The generalization is based on the two mandatory conditions: the operator equations are linear for the estimated parameters and the operators have discrete approximations. Not requiring use of iterations, this approach is well suited for hardware implementation and also for constructing the first approximation for the nonlinear least squares method. The examples of parametric problems, including the problem of estimation of parameters of some higher transcendental functions, are presented.

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