Mercuric acetate cyclization of 4-(pyrrolylmethyl)- and 4-(indolylmethyl)piperidines to bridged polycyclic systems

1983 ◽  
Vol 48 (25) ◽  
pp. 4836-4841 ◽  
Author(s):  
Joan Bosch ◽  
David Mauleon ◽  
Miguel Feliz ◽  
Ricardo Granados
Keyword(s):  
Mercuric Acetate

Oxidation of 3-carene with mercuric acetate

1965 ◽  
Vol 14 (3) ◽  
pp. 450-457 ◽  
Author(s):  
Z. G. Isaeva ◽  
B. A. Arbuzov ◽  
V. V. Ratner ◽  
I. P. Povodyreva
Keyword(s):  
Mercuric Acetate

Spectroscopic Evidence for the Formation of the Mercurous Ion in Irradiated Acetates

1971 ◽  
Vol 49 (17) ◽  
pp. 2868-2873 ◽  
Author(s):  
R. S. Eachus ◽  
F. G. Herring
Keyword(s):  
Electron Paramagnetic Resonance ◽  
Optical Spectroscopy ◽  
Mercuric Acetate ◽  
Cadmium Acetate ◽  
Γ Irradiation ◽  
Paramagnetic Resonance ◽  
Spectroscopic Evidence ◽  
Acetate Trihydrate ◽  
Electron Paramagnetic ◽  
Mercurous Ion

The Hg(I) center has been produced by γ-irradiation both in Hg(II) doped cadmium acetate trihydrate and pure mercuric acetate. Both electron paramagnetic resonance and optical spectroscopy have been used to identify this species. The results indicate that the Hg(I) ion is produced in a covalent environment.

Metal Complexes with Tetrapyrrole Ligands, XLV. The Mercuration of Nickel(II), Palladium(II), and Platinum(II) Porphyrins

1987 ◽  
Vol 42 (8) ◽  
pp. 1003-1008 ◽  
Author(s):  
Johann W. Buchler ◽  
Gerhard Herget
Keyword(s):  
Sodium Chloride ◽  
Metal Complexes ◽  
Negative Charge ◽  
Mercuric Acetate ◽  
Reaction Times ◽  
Total Density ◽  
Electrophilic Attack ◽  
Aqueous Sodium ◽  
Porphyrin Ligand ◽  
Rapid Reaction

AbstractThe mercuration of 5,10,15,20-tetrakis(4-methylphenyl)porphyrin complexes M(TTP)** (2a-c; M = Ni, Pd, Pt) is described. Treatment of Ni(TTP) (2a) with mercuric acetate in refluxing benzene and subsequently with aqueous sodium chloride yields a mixture of species M(TTP-HgnIn) (1 < n < 3) from which the monomercurial, Ni(TTP-HgCl) (3a) is isolated in 35% yield after silica chromatography. A more rapid reaction occurs with mercuric trifluoroacetate in chlorobenzene. With this system, Pd(TTP-HgCl) (3b) and Pt(TTP-HgCl) (3c) along with their bis-, tris-, and tetrakis-mercurated analogs are obtained. The reaction times indicate that replacement of NiII by PdII and PtII progressively diminishes the rate of electrophilic attack at the porphyrin periphery, consistent with a decrease of the total density of negative charge on the porphyrin ligand in these complexes.

scholarly journals Lactams. V. Syntheses of 1-(2-Arylethyl)-3-alkyl-2- and -6-piperidones : A Comparative Study of the Mercuric Acetate-EDTA and the Ferricyanide Oxidation Methods

1973 ◽  
Vol 21 (12) ◽  
pp. 2695-2704 ◽  
Author(s):  
TOZO FUJII ◽  
SHIGEYUKI YOSHIFUJI ◽  
KAZUHIKO MICHISHITA ◽  
MORIHIRO MITSUKUCHI ◽  
KIYOSHI YOSHIDA
Keyword(s):  
Comparative Study ◽  
Mercuric Acetate

scholarly journals Reaction of Octene-1 and -2 with Mercuric Acetate

1961 ◽  
Vol 82 (11) ◽  
pp. 1570-1573 ◽  
Author(s):  
Tsutomu MATSUDA ◽  
Mitsuru MORITAKE ◽  
Junyu IHARA ◽  
Saburo AKIYOSHI
Keyword(s):  
Mercuric Acetate

scholarly journals SYNTHESIS OF SECONDARY ALCOHOL COMPOUNDS FROM SAFROLE AND METHYLEUGENOL

2010 ◽  
Vol 3 (3) ◽  
pp. 176-178
Author(s):  
Hanoch J Sohilait ◽  
Hardjono Sastrohamidjojo ◽  
Sabirin Matsjeh
Keyword(s):  
1H Nmr ◽  
Sodium Borohydride ◽  
13C Nmr ◽  
Structure Elucidation ◽  
Mercuric Acetate ◽  
Secondary Alcohol ◽  
Secondary Alcohols ◽  
In Situ Reduction

Synthesis of secondary alcohols compound from safrole and methyleugenol has been achieved through conversion of allyl group to alcohol.The reaction of safrole and methyleugenol with mercuric acetate in aqueous tetrahydrofuran, followed by in situ reduction of the mercurial intermediate by alkaline sodium borohydride produced secondary alcohol namely safryl alcohol (71.25%) and methyleugenil alcohol (65.56%). The structure elucidation of these products were analyzed by FTIR, 1H-NMR, 13C-NMR and MS.   Keywords: Secondary alcohols; safrole; methyleugenol

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