Synthesis of enantiomerically pure (S)-(+)-3-hydroxytetrahydrofuran, and its (R)-enantiomer, from malic or tartaric acid

1983 ◽  
Vol 48 (16) ◽  
pp. 2767-2769 ◽  
Author(s):  
Vishnu K. Tandon ◽  
Albert M. Van Leusen ◽  
Hans Wynberg
Keyword(s):  
Tartaric Acid ◽  
Enantiomerically Pure

Synthesis of enantiomerically pure macrolides with hydrazide fragments from tetrahydropyran and l-(+)-tartaric acid derivatives

2013 ◽  
Vol 62 (1) ◽  
pp. 217-219 ◽  
Author(s):  
G. Yu. Ishmuratov ◽  
M. P. Yakovleva ◽  
G. R. Mingaleeva ◽  
M. A. Shutova ◽  
R. R. Muslukhov ◽  
...  
Keyword(s):  
Tartaric Acid ◽  
Enantiomerically Pure ◽  
Tartaric Acid Derivatives

Preparation of (4R,5S)-(5-methyl-2,2-dimethyl-1,3-dioxolane-4-ylmethyl)-phosphonium iodide. A synthetic approach to olguine: further model studies

1987 ◽  
Vol 65 (2) ◽  
pp. 332-338 ◽  
Author(s):  
Serafin Valverde ◽  
Bernardo Herradon ◽  
Rosa M. Rabanal ◽  
Manuel Martin-Lomas
Keyword(s):  
Tartaric Acid ◽  
Title Compound ◽  
Synthetic Approach ◽  
Enantiomerically Pure ◽  
Model Studies ◽  
Phosphonium Iodide ◽  
Key Steps

The enantiomerically pure title compound ((4R,5S)-(5-methyl-2,2-dimethyl-1,3-dioxolane-4-ylmethyl)-phosphonium iodide) has been synthesized starting from (R,R)-(+)-tartaric acid. The synthesis of an olguine analog has been carried out. Attempts have been made to improve the stereoselectivity and yield of key steps.

The journey of l-tartaric acid in the world of enantiomerically pure bis- and trisadducts of C60 with the inherently chiral trans-3 and all-trans-3 addition patterns

2014 ◽  
Vol 12 (43) ◽  
pp. 8574-8579 ◽  
Author(s):  
Nikos Chronakis
Keyword(s):  
Tartaric Acid ◽  
Enantiomerically Pure ◽  
The World ◽  
Inherently Chiral

The journey of l-tartaric acid through its derivative (−)-dimethyl-2,3-O-isopropylidene-l-tartrate in the synthesis of enantiomerically pure diols, cyclo-[n]-malonates and finally, inherently chiral trans-3 bisadducts and all-trans-3 trisadducts of C60 is presented.

Structural insight into the catalytic mechanism of a cis-epoxysuccinate hydrolase producing enantiomerically pure d(−)-tartaric acid

2018 ◽  
Vol 54 (61) ◽  
pp. 8482-8485 ◽  
Author(s):  
Sheng Dong ◽  
Xi Liu ◽  
Gu-Zhen Cui ◽  
Qiu Cui ◽  
Xinquan Wang ◽  
...  
Keyword(s):  
Tartaric Acid ◽  
Catalytic Mechanism ◽  
Enantiomerically Pure ◽  
Tartaric Acids ◽  
Structural Insight ◽  
Insight Into ◽  
High Stereoselectivity

The catalytic mechanism for the high stereoselectivity and product enantioselectivity of a cis-epoxysuccinate hydrolase producing d(−)-tartaric acids was elucidated.

Concise Synthesis of Enantiomerically Pure (1'S,2'R)- and (1'R,2'S)-2S-Amino-3-(2'-aminomethyl-cyclopropyl)propionic Acid: Two E-Diastereoisomers of 4,5-Methano-L-lysine

2013 ◽  
Vol 66 (9) ◽  
pp. 1105 ◽  
Author(s):  
Timothy M. Altamore ◽  
Oanh T. K. Nguyen ◽  
Quentin I. Churches ◽  
Kate Cavanagh ◽  
Xuan T. T. Nguyen ◽  
...  
Keyword(s):  
Amino Acids ◽  
Tartaric Acid ◽  
Propionic Acid ◽  
Allylic Alcohol ◽  
Allylic Alcohols ◽  
Synthetic Route ◽  
Enantiomerically Pure

A concise synthesis of both E-isomers of 2S-amino-3-(2′-aminomethyl-cyclopropyl)propionic acid, new methano-l-lysines, is described. The synthetic route includes nine steps from l-methionine, with a key step involving the cyclopropanation of an intermediate E-allylic alcohol. The resultant hydroxymethylcyclopropanes were readily separated and converted into the title α-amino acids. The stereochemistry around the cyclopropane rings was deduced by conducting the cyclopropanation in the presence of N,N,N′,N′-tetramethyl-d-tartaric acid diamide butylboronate, a chiral controller which is known to favour the production of S-hydroxymethyl cyclopropanes from allylic alcohols.

Diastereoselective formation of luminescent dinuclear lanthanide(iii) helicates with enantiomerically pure tartaric acid derived bis(β-diketonate) ligands

2007 ◽  
Vol 31 (10) ◽  
pp. 1755 ◽  
Author(s):  
Markus Albrecht ◽  
Sören Schmid ◽  
Sabrina Dehn ◽  
Claudia Wickleder ◽  
Shuang Zhang ◽  
...  
Keyword(s):  
Tartaric Acid ◽  
Enantiomerically Pure
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