Ferrier Rearrangement under Nonacidic Conditions Based on Iodonium-Induced Rearrangements of Allylic n-Pentenyl Esters, n-Pentenyl Glycosides, and Phenyl Thioglycosides

1995 ◽  
Vol 60 (12) ◽  
pp. 3851-3858 ◽  
Author(s):  
J. Cristobal Lopez ◽  
Ana M. Gomez ◽  
Serafin Valverde ◽  
Bert Fraser-Reid
Keyword(s):  
Ferrier Rearrangement ◽  
Pentenyl Glycosides

Cu-Fe Spinels: First Heterogeneous and Magnetically Recoverable Catalyst for the Ferrier Rearrangement of 2-Nitroglycals

2019 ◽  
Vol 16 (6) ◽  
pp. 447-453 ◽  
Author(s):  
Leticia Lafuente ◽  
María Florencia Rochetti ◽  
Rodolfo Bravo ◽  
Leandro Sasiambarrena ◽  
Cintia C. Santiago ◽  
...  
Keyword(s):  
Reaction Products ◽  
External Magnet ◽  
Recoverable Catalyst ◽  
Ferrier Rearrangement ◽  
Magnetically Recoverable Catalyst

Cu-Fe spinels promoted the Ferrier rearrangement of 2-nitroglycals with several O-nucleophiles. 2,3-Unsaturated carbohydrate derivatives were prepared by the reaction of 3,4,6-tri-Oacetyl- 2-nitroglucal and alcohols in the presence of 5 % of CuFe2O4. After separation of the catalyst with an external magnet, the reaction products were obtained in good yields and high stereo and regioselectivity. Also, S- and heterocyclic C-3 substituted 2-nitro-endo-glycals could be prepared by this method.

ChemInform Abstract: Recent Developments in the Ferrier Rearrangement

ChemInform ◽  
2014 ◽  
Vol 45 (5) ◽  
pp. no-no
Author(s):  
Ana M. Gomez ◽  
Fernando Lobo ◽  
Clara Uriel ◽  
J. Cristobal Lopez
Keyword(s):  
Recent Developments ◽  
Ferrier Rearrangement

ChemInform Abstract: Gold-Catalyzed Tandem Cycloisomerization/Petasis-Ferrier Rearrangement: A Direct Route to 3-Alkoxyindanones from Enynals and Alcohols.

ChemInform ◽  
2016 ◽  
Vol 47 (17) ◽  
Author(s):  
Ziping Cao ◽  
Huaqing Zhang ◽  
Xiaoxiang Zhang ◽  
Ludan Zhang ◽  
Xin Meng ◽  
...  
Keyword(s):  
Direct Route ◽  
Ferrier Rearrangement

ZnCl2/alumina impregnation catalyzed Ferrier rearrangement: an expedient synthesis of pseudoglycosides

Tetrahedron ◽  
2009 ◽  
Vol 65 (29-30) ◽  
pp. 5844-5848 ◽  
Author(s):  
Bala Kishan Gorityala ◽  
Rujee Lorpitthaya ◽  
Yaguang Bai ◽  
Xue-Wei Liu
Keyword(s):  
Ferrier Rearrangement

ChemInform Abstract: ZnCl2/Alumina Impregnation Catalyzed Ferrier Rearrangement: An Expedient Synthesis of Pseudoglycosides.

ChemInform ◽  
2009 ◽  
Vol 40 (46) ◽  
Author(s):  
Bala Kishan Gorityala ◽  
Rujee Lorpitthaya ◽  
Yaguang Bai ◽  
Xue-Wei Liu
Keyword(s):  
Ferrier Rearrangement

Microwave-induced, InCl3-catalyzed Ferrier rearrangement of acetylglycals: synthesis of 2,3-unsaturated C-glycosides

2003 ◽  
Vol 44 (24) ◽  
pp. 4507-4509 ◽  
Author(s):  
Saibal Kumar Das ◽  
K.Anantha Reddy ◽  
Chandrasekhar Abbineni ◽  
Joyita Roy ◽  
K.V.L.Narasimha Rao ◽  
...  
Keyword(s):  
Ferrier Rearrangement

Glycosyl fluorides from n-pentenyl-related glycosyl donors — Application to glycosylation strategies

2013 ◽  
Vol 91 (1) ◽  
pp. 51-65 ◽  
Author(s):  
Bert Fraser-Reid ◽  
J. Cristobal Lopez ◽  
Paloma Bernal-Albert ◽  
Ana M. Gomez ◽  
Clara Uriel ◽  
...  
Keyword(s):  
Pyridine Complex ◽  
Pentenyl Glycosides ◽  
Glycosyl Donors

n-Pentenyl glycosides (NPGs) and n-pentenyl orthoesters (NPOEs) have been transformed into glycosyl fluorides by a variety of methods. In the case of NPGs, Barluenga’s reagent, bis(pyridinium)iodonium(I)tetrafluoroborate (IPy2BF4), gives good yields of glycosyl fluorides when HF–pyridine complex is used as an additional fluoride source. NPOEs can be activated either by a combination of electrophilic iodonium (Barluenga’s reagent) and HBF4 or by the action of HF–pyridine complex. The ensuing glycosyl fluorides form a semiorthogonal pair of glycosyl donors when confronted with NPGs.

Ferrier rearrangement: an update on recent developments

2016 ◽  
pp. 210-247 ◽  
Author(s):  
Ana M. Gómez ◽  
Silvia Miranda ◽  
J. Cristobal López
Keyword(s):  
Recent Developments ◽  
Ferrier Rearrangement

Ferrier rearrangement

2002 ◽  
pp. 119-119
Author(s):  
Jie Jack Li
Keyword(s):  
Ferrier Rearrangement
Sign in / Sign up

Export Citation Format

Share Document