Photochemistry of Substituted Benzoylformate Esters. A Convenient Method for the Photochemical Oxidation of Alcohols

1995 ◽  
Vol 60 (8) ◽  
pp. 2461-2465 ◽  
Author(s):  
Michael C. Pirrung ◽  
Ronald J. Tepper
Keyword(s):  
Convenient Method ◽  
Photochemical Oxidation ◽  
Oxidation Of Alcohols

Photochemical oxidation of alcohols: Simple derivatization strategy for their analysis by capillary electrophoresis

2019 ◽  
Vol 292 ◽  
pp. 114-120 ◽  
Author(s):  
Thiago Gomes Cordeiro ◽  
Mauro Sergio Ferreira Santos ◽  
Ivano Gebhardt Rolf Gutz ◽  
Carlos D. Garcia
Keyword(s):  
Capillary Electrophoresis ◽  
Photochemical Oxidation ◽  
Oxidation Of Alcohols

CCCXVI.—The photochemical oxidation of alcohols by the dichromate ion

1927 ◽  
Vol 0 (0) ◽  
pp. 2353-2358 ◽  
Author(s):  
Edmund John Bowen ◽  
Charles William Bunn
Keyword(s):  
Photochemical Oxidation ◽  
Oxidation Of Alcohols

scholarly journals Photochemical oxidation of benzylic primary and secondary alcohols utilizing air as the oxidant

2020 ◽  
Vol 22 (2) ◽  
pp. 471-477 ◽  
Author(s):  
Nikolaos F. Nikitas ◽  
Dimitrios Ioannis Tzaras ◽  
Ierasia Triandafillidi ◽  
Christoforos G. Kokotos
Keyword(s):  
Photochemical Oxidation ◽  
Secondary Alcohols ◽  
Oxidation Of Alcohols ◽  
Aldehydes And Ketones

A mild and green photochemical protocol for the oxidation of alcohols to aldehydes and ketones was developed.

Alkoxy radical intermediates in the thermal and photochemical oxidation of alcohols

1973 ◽  
Vol 332 (1589) ◽  
pp. 151-166 ◽  
Keyword(s):  
Uranyl Nitrate ◽  
Radical Scavenging ◽  
Lead Tetraacetate ◽  
Photochemical Oxidation ◽  
Nitroso Compounds ◽  
Alkoxy Radical ◽  
Alkoxy Radicals ◽  
Radical Intermediates ◽  
Alkyl Nitrites ◽  
Oxidation Of Alcohols

Radical scavenging by nitrone and nitroso compounds, used in conjunction with e. s. r. spectroscopy, has demonstrated that alkoxy radicals are important intermediates during the thermal and photochemical oxidation of primary and secondary aliphatic alcohols: R 1 R 2 CHOH+X(ox) → R 1 R 2 CHȮH + + X(red) R 1 R 2 CHȮH + +R 1 R 2 CHOH → R 1 R 2 CHO. + R 1 R 2 CHOH + 2 R 1 R 2 CHO. + PhCH ═ NBu t → R 1 R 2 CHO─CHPh─.O─NBu t ─R 1 R 2 CHoH→R 1 R 2 C─OH + Bu t N ═ O → R 1 R 2 C─N─Bu t ─OH─O. Oxidants include the herbicidal paraquat ion, peroxydisulphate ion, the peroxydisulphatesilver (ɪ) couple, lead tetraacetate and uranyl nitrate. Independet generation of alkoxy radicals (photolysis of the corresponding alkyl nitrites R 1 R 2 CHONO) and their hydroxyalkyl isomers (H abstraction from the parent alcohol) confirms the e. s. r. assignments: mechanistic consequences of the results are discussed.

Photochemical Oxidation of Alcohols by Dichromate

Nature ◽  
1956 ◽  
Vol 177 (4515) ◽  
pp. 889-890 ◽  
Author(s):  
E. J. BOWEN
Keyword(s):  
Photochemical Oxidation ◽  
Oxidation Of Alcohols

ChemInform Abstract: PHOTOCHEMICAL OXIDATION OF ALCOHOLS USING FERRIC CHLORIDE

1977 ◽  
Vol 8 (20) ◽  
pp. no-no
Author(s):  
V. I. STENBERG ◽  
S. P. SINGH ◽  
N. K. NARAIN ◽  
S. S. PARMAR
Keyword(s):  
Ferric Chloride ◽  
Photochemical Oxidation ◽  
Oxidation Of Alcohols
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