Reactivity of carbohydrate radicals derived from iodo sugars and dibenzoyl peroxide. Homolytic heteroaromatic and aromatic substitution, reduction, and oxidation

1993 ◽  
Vol 58 (4) ◽  
pp. 959-963 ◽  
Author(s):  
Elena Vismara ◽  
Angela Donna ◽  
Francesco Minisci ◽  
Annamaria Naggi ◽  
Nadia Pastori ◽  
...  
Keyword(s):  
Aromatic Substitution ◽  
Reduction And Oxidation ◽  
Dibenzoyl Peroxide

Addition of Tetrachloromethane to 1,5-Hexadiene

1992 ◽  
Vol 57 (2) ◽  
pp. 393-396 ◽  
Author(s):  
Martin Kotora ◽  
Milan Hájek
Keyword(s):  
Palladium Catalyst ◽  
Adduct Formation ◽  
High Yield ◽  
Reaction Conditions ◽  
Dibenzoyl Peroxide

The 2 : 1 adduct as the final product of the addition of tetrachloromethane to 1,5-hexadiene catalyzed by copper(I)-butylamine complex was obtained in high yield (96%) under mild reaction conditions. Predominant 1 : 1 adduct formation was observed in the presence of a palladium catalyst or dibenzoyl peroxide initiator.

scholarly journals Machine learning meets mechanistic modelling for accurate prediction of experimental activation energies

2021 ◽  
Author(s):  
Kjell Jorner ◽  
Tore Brinck ◽  
Per-Ola Norrby ◽  
David Buttar
Keyword(s):  
Machine Learning ◽  
Activation Energies ◽  
Accurate Prediction ◽  
Nucleophilic Aromatic Substitution ◽  
Aromatic Substitution ◽  
Mechanistic Modelling

Hybrid reactivity models, combining mechanistic calculations and machine learning with descriptors, are used to predict barriers for nucleophilic aromatic substitution.

Modulation in Ru and Cu nanoparticles contents over CuAlPO-5 in synergistic enhancement in the selective reduction and oxidation of biomass-derived furan based alcohols and carbonyls

2021 ◽  
Author(s):  
Abhinav Kumar ◽  
Rajaram Bal ◽  
Rajendra Srivastava
Keyword(s):  
Selective Reduction ◽  
Value Added ◽  
Cu Nanoparticles ◽  
Platform Chemicals ◽  
Synergistic Enhancement ◽  
Reduction And Oxidation ◽  
Significant Attention ◽  
Lignocellulose Biomass

Furfural (FAL) and 5-hydroxymethylfurfural (HMF) are important and sustainable platform chemicals. They are produced from lignocellulose biomass and attract significant attention as precursors for producing value-added chemicals and fuels. The...

scholarly journals Xylochemical Synthesis and Biological Evaluation of Shancigusin C and Bletistrin G

Molecules ◽  
2021 ◽  
Vol 26 (11) ◽  
pp. 3224
Author(s):  
Leander Geske ◽  
Ulrich Kauhl ◽  
Mohamed E. M. Saeed ◽  
Anja Schüffler ◽  
Eckhard Thines ◽  
...  
Keyword(s):  
Total Synthesis ◽  
Biological Activities ◽  
Biological Evaluation ◽  
Aromatic Substitution ◽  
Substitution Reactions ◽  
Total Syntheses ◽  
Wittig Olefination ◽  
Starting Point ◽  
Perkin Reaction ◽  
Synthesis And Biological Evaluation

The biological activities of shancigusin C (1) and bletistrin G (2), natural products isolated from orchids, are reported along with their first total syntheses. The total synthesis of shancigusin C (1) was conducted by employing the Perkin reaction to forge the central stilbene core, whereas the synthesis of bletistrin G (2) was achieved by the Wittig olefination followed by several regioselective aromatic substitution reactions. Both syntheses were completed by applying only renewable starting materials according to the principles of xylochemistry. The cytotoxic properties of shancigusin C (1) and bletistrin G (2) against tumor cells suggest suitability as a starting point for further structural variation.

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