Ruthenium-catalyzed carbon-hydrogen bond activation. Oxyfunctionalization of nonactivated carbon-hydrogen bonds in the cedrane series with ruthenium tetraoxide generated in situ

1992 ◽  
Vol 57 (20) ◽  
pp. 5523-5528 ◽  
Author(s):  
A. Tenaglia ◽  
E. Terranova ◽  
B. Waegell
Keyword(s):  
Hydrogen Bond ◽  
Hydrogen Bonds ◽  
Bond Activation ◽  
Carbon Hydrogen Bond Activation ◽  
Carbon Hydrogen Bonds ◽  
Ruthenium Tetraoxide

Aerobic oxygenation catalyzed by first row transition metal complexes coordinated by tetradentate mono-carbon bridged bis-phenanthroline ligands: intra- versus intermolecular carbon–hydrogen bond activation

2019 ◽  
Vol 48 (19) ◽  
pp. 6396-6407 ◽  
Author(s):  
Kaiji Shen ◽  
Yael Diskin-Posner ◽  
Linda J. W. Shimon ◽  
Gregory Leitus ◽  
Raanan Carmieli ◽  
...  
Keyword(s):  
Hydrogen Bond ◽  
Transition Metal ◽  
Hydrogen Bonds ◽  
Metal Complexes ◽  
Transition Metal Complexes ◽  
Bond Activation ◽  
Carbon Hydrogen Bond Activation ◽  
Carbon Hydrogen Bonds ◽  
Phenanthroline Ligands

Intra- and intermolecular aerobic oxygenation is initiated by activation of carbon–hydrogen bonds and/or O2 and propagated by an autoxidation pathway.

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