A kinetic study of the electron-transfer-initiated carbon-silicon bond cleavage reactions of benzyltrialkylsilanes promoted by dodecatungstocobalt(III)ate ion

1992 ◽  
Vol 57 (17) ◽  
pp. 4684-4689 ◽  
Author(s):  
Enrico Baciocchi ◽  
Manuela Crescenzi ◽  
Elisabetta Fasella ◽  
Mario Mattioli
Keyword(s):  
Electron Transfer ◽  
Kinetic Study ◽  
Bond Cleavage ◽  
Cleavage Reactions

scholarly journals Chemistry With N-Centered Radicals Generated by Single-Electron Transfer-Oxidation Using Photoredox Catalysis

CCS Chemistry ◽  
2019 ◽  
pp. 38-49 ◽  
Author(s):  
Heng Jiang ◽  
Armido Studer
Keyword(s):  
Electron Transfer ◽  
Recent Literature ◽  
Bond Cleavage ◽  
Photoredox Catalysis ◽  
Proton Coupled Electron Transfer ◽  
Cascade Processes ◽  
Reactive N ◽  
Radical Generation ◽  
Cleavage Reactions ◽  
Oxidative Generation

This review covers the recent literature on oxidative generation of N-centered radicals using photoredox catalysis. The concept of proton-coupled electron transfer is briefly discussed. Applications of such reactive N-centered radicals in cascade processes comprising arene amidation, alkene amidation, C—C bond cleavage reactions, and remote C—H functionalization are addressed. In addition, novel reagents allowing for clean oxidative N-radical generation are discussed.

ChemInform Abstract: Carbon-Oxygen Bond-Cleavage Reactions by Electron Transfer. Part 4. Electrochemical and Alkali-Metal Reductions of Phenoxynaphthalenes.

ChemInform ◽  
1989 ◽  
Vol 20 (29) ◽  
Author(s):  
T. A. THORNTON ◽  
G. A. ROSS ◽  
D. PATIL ◽  
K. MUKAIDA ◽  
J. O. WARWICK ◽  
...  
Keyword(s):  
Electron Transfer ◽  
Alkali Metal ◽  
Bond Cleavage ◽  
Cleavage Reactions ◽  
Oxygen Bond
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