Addition of racemic alkoxyallylstannanes to an enantiomerically pure 2-methoxyoxazolidine: an example of combined mutual diastereoface selection and kinetic resolution

1991 ◽  
Vol 56 (25) ◽  
pp. 6961-6963 ◽  
Author(s):  
Anna Bernardi ◽  
Giovanni Poli ◽  
Carlo Scolastico ◽  
Matteo Zanda
Keyword(s):  
Kinetic Resolution ◽  
Enantiomerically Pure

Stereochemistry of epoxide carbonylation using bimetallic Lewis acid/metal carbonyl complexes

2004 ◽  
Vol 76 (3) ◽  
pp. 557-564 ◽  
Author(s):  
Y. D. Y. L. Getzler ◽  
Viswanath Mahadevan ◽  
E. B. Lobkovsky ◽  
G. W. Coates
Keyword(s):  
Lewis Acid ◽  
Kinetic Resolution ◽  
Metal Carbonyl ◽  
Carbonyl Complexes ◽  
Enantiomerically Pure ◽  
Metal Carbonyl Complexes ◽  
Pure Complex

The stereochemistry of epoxide carbonylation using bimetallic [Lewis acid]+[Co(CO)4]- complexes is reported. The achiral complex [(salph)Al(THF)2][Co(CO)4] stereospecifically carbonylates cis- and trans-2-butene oxide to the trans- and cis-β-lactones, respectively. Preliminary experiments regarding the carbonylative kinetic resolution of racemic trans-2-butene oxide using the enantiomerically pure complex [(R,R-salcy)Al(THF)2][Co(CO)4] are also reported.

scholarly journals Synthesis of enantiomerically pure alcohols and amines via biocatalytic deracemisation methods

2019 ◽  
Vol 9 (20) ◽  
pp. 5487-5503 ◽  
Author(s):  
Musa M. Musa ◽  
Frank Hollmann ◽  
Francesco G. Mutti
Keyword(s):  
Kinetic Resolution ◽  
Enantiomeric Excess ◽  
Enantiomerically Pure ◽  
Theoretical Maximum

Deracemisation via chemo-enzymatic or multi-enzymatic approaches is the optimum substitute for kinetic resolution, which suffers from the limitation of a theoretical maximum 50% yield albeit high enantiomeric excess is attainable.

scholarly journals Continuous Flow Preparation of Enantiomerically Pure BINOL(s) by Acylative Kinetic Resolution

2020 ◽  
Vol 362 (6) ◽  
pp. 1370-1377 ◽  
Author(s):  
Junshan Lai ◽  
Rifahath M. Neyyappadath ◽  
Andrew D. Smith ◽  
Miquel A. Pericàs
Keyword(s):  
Continuous Flow ◽  
Kinetic Resolution ◽  
Enantiomerically Pure

ChemInform Abstract: Dynamic Kinetic Resolution of Homoallylic Alcohols: Application to the Synthesis of Enantiomerically Pure 5,6-Dihydropyran-2-ones and δ-Lactones.

ChemInform ◽  
2014 ◽  
Vol 45 (12) ◽  
pp. no-no
Author(s):  
Madeleine C. Warner ◽  
Grigory A. Shevchenko ◽  
Suzan Jouda ◽  
Krisztian Bogar ◽  
Jan-E. Baeckvall
Keyword(s):  
Kinetic Resolution ◽  
Dynamic Kinetic Resolution ◽  
Enantiomerically Pure ◽  
Homoallylic Alcohols
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