New agents for the selective reduction of the carbon-carbon double bond of .alpha.,.beta.-unsaturated carbonyl compounds

1991 ◽  
Vol 56 (23) ◽  
pp. 6720-6722 ◽  
Author(s):  
Yutaka Nishiyama ◽  
Masanori Yoshida ◽  
Shigeo Ohkawa ◽  
Sawako Hamanaka
2000 ◽  
Vol 78 (11) ◽  
pp. 1396-1398 ◽  
Author(s):  
Moni Chauhan ◽  
Philip Boudjouk

A variety of α,β-unsaturated esters and cyclic ketones underwent smooth reduction of the carbon–carbon double bond with a combination of inexpensive and readily available trichlorosilane and CoCl2. The reactions are performed under very mild conditions and products are obtained in high yields.Key words: reduction, carbonyl compounds, trichlorosilane, ketones, chemoselectivity.


1987 ◽  
Vol 60 (9) ◽  
pp. 3421-3422 ◽  
Author(s):  
Takashi Sakai ◽  
Kazuyoshi Miyata ◽  
Kazuomi Hondo ◽  
Masanori Utaka ◽  
Akira Takeda

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