Crown Ether Complexed Alkali Metal Picrate Ion Pairs in Water-Saturated Dichloromethane As Studied by Electrolytic Conductance and by Partitioning into Water. Effect of Lithium Chloride on Partitioning

1997 ◽  
Vol 42 (1) ◽  
pp. 49-53 ◽  
Author(s):  
Izaak M. Kolthoff ◽  
Miran K. Chantooni
Keyword(s):  
Crown Ether ◽  
Alkali Metal ◽  
Lithium Chloride ◽  
Ion Pairs ◽  
Water Effect ◽  
Electrolytic Conductance ◽  
Metal Picrate ◽  
Water Saturated

PEO-based electrolytes blended with star polymers with precisely imprinted polymeric pseudo-crown ether cavities for alkali metal ion batteries

2019 ◽  
Vol 576 ◽  
pp. 182-189 ◽  
Author(s):  
Zhuliu Xiao ◽  
Binghua Zhou ◽  
Jirong Wang ◽  
Cai Zuo ◽  
Dan He ◽  
...  
Keyword(s):  
Crown Ether ◽  
Alkali Metal ◽  
Metal Ion ◽  
Star Polymers ◽  
Alkali Metal Ion

Conformational effect on the preferential binding of alkali metal cation with crown ether: A molecular level investigation

2009 ◽  
Vol 12 (1-3) ◽  
pp. 93-99 ◽  
Author(s):  
Sulagna De ◽  
Sk. Musharaf Ali ◽  
M.R.K. Shenoi ◽  
Sandip K. Ghosh ◽  
Dilip K. Maity
Keyword(s):  
Crown Ether ◽  
Alkali Metal ◽  
Metal Cation ◽  
Molecular Level ◽  
Alkali Metal Cation ◽  
Conformational Effect ◽  
Preferential Binding

Synthesis and alkali metal picrate extraction studies of lower rim functionalized p-tert-butylcalix[4]arene crown ethers

Tetrahedron ◽  
2002 ◽  
Vol 58 (51) ◽  
pp. 10205-10212 ◽  
Author(s):  
Alan P Marchand ◽  
Hyun-Soon Chong ◽  
T Pavan Kumar ◽  
Zilin Huang ◽  
Sulejman Alihodzic ◽  
...  
Keyword(s):  
Alkali Metal ◽  
Crown Ethers ◽  
Metal Picrate ◽  
Picrate Extraction ◽  
Alkali Metal Picrate Extraction

Solution Properties of Tetraalkylammonium Halide and Alkali-Metal Halide Ion Pairs. The Relationship Between Dissociation Constants and Solubility Products

1987 ◽  
Vol 40 (7) ◽  
pp. 1201 ◽  
Author(s):  
W Mizerski ◽  
MK Kalinowski
Keyword(s):  
Alkali Metal ◽  
Solubility Product ◽  
Dissociation Constants ◽  
Ion Pairs ◽  
Empirical Relation ◽  
Alkali Metal Halide ◽  
Alkali Metal Cations ◽  
Solubility Products ◽  
The Relationship ◽  
Dissociation Constant Kd

An empirical relation describing the effect of solvent on the dissociation constant ( Kd ) of ion pairs is described. An equation of the form pKd = apKso + bD-1 + c ( Kso and D stand for the solubility product of a given salt and for the electric permittivity of a solvent, respectively) has been tested with 13 sets of experimental data for salts containing tetraalkylammonium and alkali-metal cations. A successful correlation was obtained in 100% of the cases considered.

The Influence of Alkali Metal Cation Size on the Formation and Dissociation of Crown Ether Fullerene Dimers in Electrospray Mass Spectrometry

2015 ◽  
Vol 120 (1) ◽  
pp. 786-792 ◽  
Author(s):  
Ina D. Kellner ◽  
Marc S. von Gernler ◽  
Manolis D. Tzirakis ◽  
Michael Orfanopoulos ◽  
Thomas Drewello
Keyword(s):  
Mass Spectrometry ◽  
Crown Ether ◽  
Alkali Metal ◽  
Metal Cation ◽  
Electrospray Mass Spectrometry ◽  
Alkali Metal Cation ◽  
Fullerene Dimers ◽  
Cation Size

Axle component separated ion-pair recognition by a neutral heteroditopic [2]rotaxane

2014 ◽  
Vol 50 (13) ◽  
pp. 1540-1542 ◽  
Author(s):  
Richard C. Knighton ◽  
Paul D. Beer
Keyword(s):  
Alkali Metal ◽  
Metal Cation ◽  
Alkali Metal Cation ◽  
Ion Pairs ◽  
Ion Pair ◽  
Sodium Cation ◽  
Halide Anion ◽  
Cooperative Recognition

A neutral heteroditopic pyridine N-oxide axle containing [2]rotaxane, synthesised via sodium cation templation, displays cooperative recognition of alkali metal cation-halide anion ion-pairs in an unprecedented axle component separated ion-pair binding fashion.

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