Thermodynamic properties of gases in propellants. Solubilities of gaseous ammonia, carbon monoxide, carbon dioxide, and sulfur hexafluoride

1971 ◽  
Vol 16 (4) ◽  
pp. 404-408 ◽  
Author(s):  
Elfreda T. Chang ◽  
Nev A. Gokcen ◽  
Talmadge M. Poston
Keyword(s):  
Carbon Dioxide ◽  
Carbon Monoxide ◽  
Thermodynamic Properties ◽  
Sulfur Hexafluoride ◽  
Gaseous Ammonia

Appropriate Mean Absorption Coefficients for Infrared Radiation of Gases

1967 ◽  
Vol 89 (4) ◽  
pp. 321-327 ◽  
Author(s):  
M. M. Abu-Romia ◽  
C. L. Tien
Keyword(s):  
Carbon Dioxide ◽  
Heat Flux ◽  
Carbon Monoxide ◽  
Water Vapor ◽  
Thermodynamic Properties ◽  
Infrared Radiation ◽  
Radiative Heat ◽  
Radiative Heat Flux ◽  
Absorption Coefficients ◽  
Planar Medium

In this paper, a study is made on the calculation of appropriate mean absorption coefficients for the infrared radiation of gases. The Planck and Rosseland mean absorption coefficients for the optically thin and optically thick gases are expressed as functions of the spectroscopic and thermodynamic properties of the gas. Values of the Planck and Rosseland mean absorption coefficients are presented for carbon monoxide, carbon dioxide, and water vapor in the temperature range from 1000 to 5000 deg Rankine. To illustrate the application of these results, the radiative heat flux is calculated for the simple case of a planar medium.

scholarly journals Investigation of the Effects of Steam Injection on Equilibrium Products and Thermodynamic Properties of Diesel and Biodiesel Fuels

2020 ◽  
Vol 2020 ◽  
pp. 1-14
Author(s):  
Jean Paul Gram Shou ◽  
Marcel Obounou ◽  
Timoléon Crépin Kofané ◽  
Mahamat Hassane Babikir
Keyword(s):  
Nitric Oxide ◽  
Carbon Dioxide ◽  
Carbon Monoxide ◽  
Thermodynamic Properties ◽  
Specific Heat ◽  
Steam Injection ◽  
Combustion Products ◽  
Waste Cooking Oil ◽  
Cooking Oil ◽  
Biodiesel Fuels

The effects of steam injection on combustion products and thermodynamic properties of diesel fuel, soybean oil-based biodiesel (NBD), and waste cooking oil biodiesel (WCOB) are examined in this study by considering the chemical equilibrium. The model gives equilibrium mole fractions, specific heat of the exhaust mixtures of 10 combustion products, and adiabatic flame temperatures. The results show that the mole fractions of carbon monoxide (CO) and carbon dioxide (CO2) decrease with the steam injection ratios. Nitric oxide (NO) mole fractions decrease with the steam injections ratios for lean mixtures. The specific heat of combustion products increases with the steam injection ratios. The equilibrium combustion products obtained can be used to calculate the nonequilibrium values of NO in the exhaust gases using some existing correlations of NO kinetics.

scholarly journals Controlled atmosphere GMAW welding of transportation vehicles and production machines parts made from 30MnB5 steel

2018 ◽  
Vol 216 ◽  
pp. 03001 ◽  
Author(s):  
Evgeny Ivanayskiy ◽  
Aleksei Ishkov ◽  
Aleksandr Ivanayskiy ◽  
Iakov Ochakovskii
Keyword(s):  
Mechanical Properties ◽  
Carbon Dioxide ◽  
Carbon Monoxide ◽  
Chemical Composition ◽  
Controlled Atmosphere ◽  
Shielding Gas ◽  
Reducing Atmosphere ◽  
Metal Composition ◽  
Gmaw Welding ◽  
Welding Materials

The paper studies the influence of shielding gas on the composition and the structure of weld joint metal of 30MnB5 steel applied in essential parts of automobiles and tractors. The welding was performed in inert, oxidizing and reducing atmospheres. It was established that TIG welding with argon used as shielding gas did not provide the required mechanical properties when using conventional welding materials. Carbon dioxide during MAG welding caused partial burning of alloying elements. Carbon monoxide used as shielding gas was proved to form reducing atmosphere enabling to obtain chemical composition close to the base metal composition. Metallographic examinations were carried out. The obtained results provided full-strength weld, as well as the required reliability and durability of welded components and joints.

Low-Carbon Monoxide Hydrogen by Sorption-Enhanced Reaction

2003 ◽  
Vol 1 (1) ◽  
Author(s):  
Douglas P Harrison ◽  
Zhiyong Peng
Keyword(s):  
Carbon Dioxide ◽  
Carbon Monoxide ◽  
Hydrogen Production ◽  
Proton Exchange Membrane ◽  
Primary Energy ◽  
Proton Exchange ◽  
Raw Material ◽  
Impurity Level ◽  
Low Carbon ◽  
Enhanced Production

Hydrogen is an increasingly important chemical raw material and a probable future primary energy carrier. In many current and anticipated applications the carbon monoxide impurity level must be reduced to low-ppmv levels to avoid poisoning catalysts in downstream processes. Methanation is currently used to remove carbon monoxide in petroleum refining operations while preferential oxidation (PROX) is being developed for carbon monoxide control in fuel cells. Both approaches add an additional step to the multi-step hydrogen production process, and both inevitably result in hydrogen loss. The sorption enhanced process for hydrogen production, in which steam-methane reforming, water-gas shift, and carbon dioxide removal reactions occur simultaneously in the presence of a nickel-based reforming catalyst and a calcium-based carbon dioxide sorbent, is capable of producing high purity hydrogen containing minimal carbon monoxide in a single processing step. The process also has the potential for producing pure CO2 that is suitable for subsequent use or sequestration during the sorbent regeneration step. The current research on sorption-enhanced production of low-carbon monoxide hydrogen is an extension of previous research in this laboratory that proved the feasibility of producing 95+% hydrogen (dry basis), but without concern for the carbon monoxide concentration. This paper describes sorption-enhanced reaction conditions – temperature, feed gas composition, and volumetric feed rate – required to produce 95+% hydrogen containing low carbon monoxide concentrations suitable for direct use in, for example, a proton exchange membrane fuel cell.

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