Solid State Reaction Study of Chromium Trioxide and Chromium(ic) Oxide with the Hydrated Nitrates of Copper and Zinc.

1966 ◽  
Vol 11 (4) ◽  
pp. 582-583 ◽  
Author(s):  
W. M. Keely ◽  
W. B. Mathes
2000 ◽  
Vol 346 (1-2) ◽  
pp. 115-132 ◽  
Author(s):  
V. Berbenni ◽  
A. Marini ◽  
G. Bruni ◽  
R. Riccardi

1989 ◽  
Vol 32-33 ◽  
pp. 398-408 ◽  
Author(s):  
A MARINI ◽  
V BERBENNI ◽  
V MASSAROTTI ◽  
G FLOR ◽  
R RICCARDI ◽  
...  

2012 ◽  
Vol 67 (7) ◽  
pp. 667-672 ◽  
Author(s):  
Vittorio Berbenni ◽  
Chiara Milanese ◽  
Giovanna Bruni ◽  
Alessandro Girella ◽  
Amedeo Marini

The synthesis of barium metastannate, BaSnO3, by heating mixtures of metal oxalates, either physically mixed or subjected to a phase of mechanical activation, up to temperatures in the range 750- 1200 °C has been studied. Simultaneous thermogravimetric-differential scanning calorimetric (TGDSC) analyses and powder X-ray diffractometry have been applied to check the advancement of the reactions. BaSnO3, though slightly contaminated by BaCO3, can be obtained by heating the activated mixture up to T ≥ 1000 °C while heating a sample of a physical mixture at temperature as high as 1200 °C resulted in a mixture of BaSnO3, SnO2 and Ba2SnO4. The heat capacities of BaSnO3 samples prepared at temperatures between 1000 and 1200 °C have been measured by modulated temperature differential scanning calorimetry (MTDSC) in the temperature range 50-400 °C.


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