scholarly journals Activity Coefficients at Infinite Dilution for Organic Solutes Dissolved in Three 1-Alkyl-1-methylpyrrolidinium Bis(trifluoromethylsulfonyl)imide Ionic Liquids Bearing Short Linear Alkyl Side Chains of Three to Five Carbons

2013 ◽  
Vol 58 (8) ◽  
pp. 2210-2218 ◽  
Author(s):  
Fabrice Mutelet ◽  
El-Sayed R. E. Hassan ◽  
Timothy W. Stephens ◽  
William E. Acree ◽  
Gary A. Baker
Keyword(s):  
Ionic Liquids ◽  
Activity Coefficients ◽  
Infinite Dilution ◽  
Side Chains ◽  
Organic Solutes ◽  
Alkyl Side Chains

scholarly journals Imidazolium Based Ionic Liquids: Unbiased Recovering of Vaporization Enthalpies from Infinite-Dilution Activity Coefficients

Molecules ◽  
2021 ◽  
Vol 26 (19) ◽  
pp. 5873
Author(s):  
Sergey P. Verevkin
Keyword(s):  
Ionic Liquids ◽  
General Formula ◽  
Activity Coefficients ◽  
Infinite Dilution ◽  
Reference Temperature ◽  
Organic Solutes ◽  
Imidazolium Cation ◽  
Infinite Dilution Activity Coefficients ◽  
Efficient Approach ◽  
Volatile Organic

We propose and test an efficient approach for the assessment of the enthalpies of vaporization of ionic liquids at the reference temperature 298.15 K. The approach is based on activity coefficients at infinite dilution of volatile organic solutes in ionic liquids bearing the imidazolium cation of the general formula [Cnmim][Anion].

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