Liquid–Liquid Equilibrium for the Glycerol + Alcohol + Coconut Biodiesel System at Different Temperatures and Atmospheric Pressure

2012 ◽  
Vol 57 (12) ◽  
pp. 3557-3562 ◽  
Author(s):  
Francisca Maria R. Mesquita ◽  
Nathan Sombra Evangelista ◽  
Hosiberto Batista de Sant’Ana ◽  
Rílvia Saraiva de Santiago-Aguiar
Keyword(s):  
Atmospheric Pressure ◽  
Liquid Equilibrium ◽  
Different Temperatures

Liquid–liquid equilibrium data for the systems {LTTM+benzene+hexane} and {LTTM+ethyl acetate+hexane} at different temperatures and atmospheric pressure

2013 ◽  
Vol 360 ◽  
pp. 54-62 ◽  
Author(s):  
Agustin S.B. Gonzalez ◽  
María Francisco ◽  
Guillermo Jimeno ◽  
Sara Lago García de Dios ◽  
Maaike C. Kroon
Keyword(s):  
Ethyl Acetate ◽  
Atmospheric Pressure ◽  
Liquid Equilibrium ◽  
Equilibrium Data ◽  
Different Temperatures

Measurement and Correlation for Vapor Pressure and Excess Enthalpy of the New Working Pairs：Water/Ethanol/Methanol + Ionic Liquids 1-Ethyl-3-Methylimidazolium Diethylphosphate

2012 ◽  
Vol 524-527 ◽  
pp. 1697-1701 ◽  
Author(s):  
Xiao Dong Zhang ◽  
Da Peng Hu ◽  
Zong Chang Zhao
Keyword(s):  
Atmospheric Pressure ◽  
Excess Enthalpy ◽  
Heat Pumps ◽  
Negative Deviation ◽  
Liquid Equilibrium ◽  
Relative Deviation ◽  
Strong Negative Deviation ◽  
Different Temperatures ◽  
Absorption Cycle ◽  
Activity Coefficient Models

Three binary solutions composed of ionic liquid (IL), 1-ethyl-3-methylimidazolium diethylphosphate ([EMIM] [DEP]), and selected refrigerants (water, ethanol or methanol) were proposed as new working pairs for absorption heat pumps or absorption refrigerators. The vapor–liquid equilibrium (VLE) data were measured by a static method at different temperatures and at different ILs mole factions and correlated by the None-Random Two Liquids (NRTL) activity coefficient models, and the average relative deviation were less than 3.3%. The solutions showed strong negative deviation from the Raoult's Law and were able to absorb vapor of water, ethanol or methanol. The excess enthalpies were measured and correlated at 298.15 K and atmospheric pressure. The results indicated that the mixing of [EMIM] [DEP] with water, ethanol or methanol were exothermal. The proposed solutions were proved to possess one of the fundamental features that a working pair must have in absorption cycle.

Vapour-liquid equilibrium in the isobutyl formate-isobutyl alcohol and n-butyl formate-isobutyl alcohol systems at atmospheric pressure

1979 ◽  
Vol 44 (12) ◽  
pp. 3501-3508 ◽  
Author(s):  
Jan Linek
Keyword(s):  
Experimental Data ◽  
Fourth Order ◽  
Atmospheric Pressure ◽  
Isobutyl Alcohol ◽  
Liquid Equilibrium ◽  
The Third

Isobaric vapour-liquid equilibria in the isobutyl formate-isobutyl alcohol and n-butyl formate-isobutyl alcohol systems have been measured at atmospheric pressure. A modified circulation still of the Gillespie type has been used for the measurements. The experimental data have been correlated by means of the third- and fourth-order Margules equations.

Liquid-liquid equilibrium in binary glycols-toluene and glycols-xylene systems

1982 ◽  
Vol 47 (6) ◽  
pp. 1686-1694 ◽  
Author(s):  
Lumír Mandík ◽  
František Lešek
Keyword(s):  
Atmospheric Pressure ◽  
Binary Systems ◽  
Liquid Equilibrium ◽  
Benzene Toluene

Liquid-liquid equilibria were determined in the following binary systems: 1,2-ethandiol/toluene, 1,2-ethandiol/xylene, 1,2-propandiol/toluene, 1,2-propandiol/xylene, 1,4-butandiol/toluene, 1,4-butandiol/xylene, 1,3-butandiol/toluene, 1,3-butandiol/xylene, 1,3-butandiol/p-xylene, 2,2'-dioxydiethanol/toluene, 2,2'-dioxydiethanol/xylene. The solubility of 2,2-dimethyl-1,3-propandiol in benzene, toluene and xylene was also measured. Critical solubility temperatures at atmospheric pressure were determined for systems containing 1,2-propandiol and 1,3-butandiol.

scholarly journals Thermal Conductivities of Choline Chloride-Based Deep Eutectic Solvents and Their Mixtures with Water: Measurement and Estimation

Molecules ◽  
2020 ◽  
Vol 25 (17) ◽  
pp. 3816
Author(s):  
Taleb H. Ibrahim ◽  
Muhammad A. Sabri ◽  
Nabil Abdel Jabbar ◽  
Paul Nancarrow ◽  
Farouq S. Mjalli ◽  
...  
Keyword(s):  
Atmospheric Pressure ◽  
Choline Chloride ◽  
Deep Eutectic Solvents ◽  
Standard Uncertainty ◽  
Heat Transfer Fluids ◽  
Wide Range ◽  
Different Temperatures ◽  
Experimental Values ◽  
Water Measurement ◽  
Thermal Conductivities

The thermal conductivities of selected deep eutectic solvents (DESs) were determined using the modified transient plane source (MTPS) method over the temperature range from 295 K to 363 K at atmospheric pressure. The results were found to range from 0.198 W·m−1·K−1 to 0.250 W·m−1·K−1. Various empirical and thermodynamic correlations present in literature, including the group contribution method and mixing correlations, were used to model the thermal conductivities of these DES at different temperatures. The predictions of these correlations were compared and consolidated with the reported experimental values. In addition, the thermal conductivities of DES mixtures with water over a wide range of compositions at 298 K and atmospheric pressure were measured. The standard uncertainty in thermal conductivity was estimated to be less than ± 0.001 W·m−1·K−1 and ± 0.05 K in temperature. The results indicated that DES have significant potential for use as heat transfer fluids.

Molecular Interactions Investigation of L-Histidine in Water and in Aqueous Citric Acid at Different Temperatures Using Volumetric and Acoustic Methods

2018 ◽  
Vol 232 (3) ◽  
pp. 393-408 ◽  
Author(s):  
Dinesh Kumar ◽  
Shashi Kant Sharma
Keyword(s):  
Citric Acid ◽  
Molar Volume ◽  
Atmospheric Pressure ◽  
Apparent Molar Volume ◽  
Adiabatic Compressibility ◽  
Acid Solutions ◽  
Solvent Interactions ◽  
Intermolecular Free Length ◽  
Acoustic Methods ◽  
Different Temperatures

AbstractDensities,ρand ultrasonic speeds, u of L-histidine (0.02–0.12 mol·kg−1) in water and 0.1 mol·kg−1aqueous citric acid solutions were measured over the temperature range (298.15–313.15) K with interval of 5 K at atmospheric pressure. From these experimental data apparent molar volume ΦV, limiting apparent molar volume ΦVOand the slopeSV, partial molar expansibilities ΦEO, Hepler’s constant, adiabatic compressibilityβ, transfer volume ΦV, trO, intermolecular free length (Lf), specific acoustic impedance (Z) and molar compressibility (W) were calculated. The results are interpreted in terms of solute–solute and solute–solvent interactions in these systems. It has also been observed that L-histidine act as structure maker in water and aqueous citric acid.

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