scholarly journals Activity Coefficients at Infinite Dilution of Organic Compounds in Four New Imidazolium-Based Ionic Liquids

2011 ◽  
Vol 56 (7) ◽  
pp. 3106-3114 ◽  
Author(s):  
Jean-Charles Moïse ◽  
Fabrice Mutelet ◽  
Jean-Noël Jaubert ◽  
Laura M. Grubbs ◽  
William E. Acree ◽  
...  
Keyword(s):  
Ionic Liquids ◽  
Organic Compounds ◽  
Activity Coefficients ◽  
Infinite Dilution

scholarly journals Measurements of Activity Coefficients at Infinite Dilution for Organic Solutes in the Ionic Liquids N-Ethyl- and N-Octyl-N-methylmorpholinium Bis(trifluoromethanesulfonyl)imide. A Useful Tool for Solvent Selection

Molecules ◽  
2020 ◽  
Vol 25 (3) ◽  
pp. 634 ◽  
Author(s):  
Łukasz Marcinkowski ◽  
Joachim Eichenlaub ◽  
Elham Ghasemi ◽  
Żaneta Polkowska ◽  
Adam Kloskowski
Keyword(s):  
Ionic Liquids ◽  
Organic Compounds ◽  
Activity Coefficients ◽  
Infinite Dilution ◽  
Retention Data ◽  
Separation Processes ◽  
Study Results ◽  
Conscious Choice ◽  
Potential Applications ◽  
Partial Molar Enthalpies

In recent years, many papers describing ionic liquids (IL) as promising solvents in separation techniques have been published. The conscious choice of appropriate ionic liquid as absorption media in effective extraction of selected types of analytes requires deeper understanding of the analyte−IL interactions. Therefore, intensive research is conducted to determine the values of activity coefficient at infinite dilution, which allows us to characterize the nature of these interactions. Based on the inverse gas chromatography retention data, activity coefficients at infinite dilution γ 13 ∞ of 48 different organic compounds in the ionic liquids N-ethyl-N-methylmorpholinium bis(trifluoromethanesulfonyl)imide [C2C1Mor][TFSI] and N-octyl-N-methylmorpholinium bis(trifluoromethanesulfonyl)imide [C8C1Mor][TFSI] were determined. The measurements covered a broad range of volatile organic compounds, including n-alkanes, n-alkenes, n-alkynes, alcohols, aldehydes, ketones, aromatic compounds and common polar solvents, representing different types of interactions. Activity coefficients at infinite dilution were measured in the temperature range from 313.15 to 363.15 K. The excess partial molar enthalpies and entropies at infinite dilution were determined. Selectivity at infinite dilution was also calculated for exemplary separation processes in the hexane/benzene system. The obtained results were analyzed and compared with literature data for ionic liquids containing the same anion [TFSI]¯ and different cations. The study results indicate that some potential applications of the investigated ionic liquids in separation problems exist.

Activity Coefficients at Infinite Dilution of Organic Compounds in 1-(Meth)acryloyloxyalkyl-3-methylimidazolium Bromide Using Inverse Gas Chromatography

2008 ◽  
Vol 112 (12) ◽  
pp. 3773-3785 ◽  
Author(s):  
Fabrice Mutelet ◽  
Jean-Noël Jaubert ◽  
Marek Rogalski ◽  
Julie Harmand ◽  
Michèle Sindt ◽  
...  
Keyword(s):  
Gas Chromatography ◽  
Organic Compounds ◽  
Activity Coefficients ◽  
Infinite Dilution ◽  
Inverse Gas Chromatography
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