Densities and Viscosities for Binary Mixtures of 1-Butyl-3-Methylimidazolium Tetrafluoroborate Ionic Liquid with Molecular Solvents

2011 ◽  
Vol 56 (4) ◽  
pp. 1526-1534 ◽  
Author(s):  
Oana Ciocirlan ◽  
Oana Croitoru ◽  
Olga Iulian
Keyword(s):  
Ionic Liquid ◽  
Binary Mixtures ◽  
Molecular Solvents

Solvatochromism of Binary Mixtures of 2,2,2-Trifluoroethanol + Ionic Liquid [bmim][Tf2N]: A Comparative Study with Molecular Solvents

2019 ◽  
Vol 64 (3) ◽  
pp. 1140-1154 ◽  
Author(s):  
Md Rabiul Islam ◽  
Faiz Warsi ◽  
Abbul Bashar Khan ◽  
Tasneem Kausar ◽  
Imran Khan ◽  
...  
Keyword(s):  
Ionic Liquid ◽  
Comparative Study ◽  
Binary Mixtures ◽  
Molecular Solvents

scholarly journals Solvatochromic parameters for binary mixtures of an ionic liquid with various protic molecular solvents

2008 ◽  
Vol 140 (3) ◽  
pp. 329-334 ◽  
Author(s):  
Mohammad Khodadadi-Moghaddam ◽  
Aziz Habibi-Yangjeh ◽  
Mohamad Reza Gholami
Keyword(s):  
Ionic Liquid ◽  
Binary Mixtures ◽  
Solvatochromic Parameters ◽  
Molecular Solvents

Solvation properties of protic ionic liquid–molecular solvent mixtures

2020 ◽  
Vol 22 (19) ◽  
pp. 10995-11011 ◽  
Author(s):  
Dilek Yalcin ◽  
Andrew J. Christofferson ◽  
Calum J. Drummond ◽  
Tamar L. Greaves
Keyword(s):  
Ionic Liquid ◽  
Binary Mixtures ◽  
Binary Solvent ◽  
Solvent Mixtures ◽  
Protic Ionic Liquid ◽  
Ethylammonium Nitrate ◽  
Binary Solvent Systems ◽  
Solvent Systems ◽  
Molecular Solvents

In this study, we have investigated the solvation properties of binary mixtures of PILs with molecular solvents. The selected binary solvent systems are the PILs ethylammonium nitrate (EAN) and propylammonium nitrate (PAN) combined with either water, methanol, acetonitrile or DMSO.

scholarly journals Solvatochromic And Fluorescence Spectroscopic Studies On Polarity Of Ionic Liquid And Ionic Liquid-Based Binary Systems

2013 ◽  
Vol 25 (2) ◽  
pp. 146-158 ◽  
Author(s):  
Kumkum Ahmed ◽  
Anika Auni ◽  
Gulshan Ara ◽  
MM Rahman ◽  
M Yousuf Aa Mollah ◽  
...  
Keyword(s):  
Ionic Liquid ◽  
Binary Mixtures ◽  
Binary Systems ◽  
Spectroscopic Method ◽  
Specific Interaction ◽  
Chemical Society ◽  
Spectroscopic Studies ◽  
The Other ◽  
Relative Merit ◽  
Molecular Solvents

Polarity behavior of a hydrophobic ionic liquid (IL) 1-ethyl-3-methylimidazolium bis(trifluoromethyl)sulphonylimide [EMI][TFSI] and binary mixtures of [EMI][TFSI] with ethanol, acetone and dichloromethane was investigated by solvatochromic method using Reichardt’s betaine dye. Fluorescence spectroscopic method using pyrene as a probe was also used for estimation of polarity of [EMI][TFSI] and [EMI][TFSI]-based binary systems. The binary mixtures of [EMI][TFSI] with the molecular solvents interestingly showed increase in polarity with increasing [EMI][TFSI] for all compositions. The comparative and contrastive features of the results of two methods have been discussed to judge relative merit of one method over the other. Both of the methods collectively provided information to correlate specific interaction of the IL with molecular solvents and define polarity behavior. Journal of Bangladesh Chemical Society, Vol. 25(2), 146-158, 2012 DOI: http://dx.doi.org/10.3329/jbcs.v25i2.15067

Absorption Behavior of Acid Gases in Protic Ionic Liquid/Alkanolamine Binary Mixtures

2017 ◽  
Vol 5 (4) ◽  
pp. 3429-3437 ◽  
Author(s):  
Alsu I. Akhmetshina ◽  
Anton N. Petukhov ◽  
Andrey V. Vorotyntsev ◽  
Alexander V. Nyuchev ◽  
Ilya V. Vorotyntsev
Keyword(s):  
Ionic Liquid ◽  
Binary Mixtures ◽  
Acid Gases ◽  
Protic Ionic Liquid

Temperature-Driven Mixing-Demixing Behavior of Binary Mixtures of the Ionic Liquid Choline Bis(trifluoromethylsulfonyl)imide and Water

2009 ◽  
Vol 113 (5) ◽  
pp. 1429-1437 ◽  
Author(s):  
Peter Nockemann ◽  
Koen Binnemans ◽  
Ben Thijs ◽  
Tatjana N. Parac-Vogt ◽  
Klaus Merz ◽  
...  
Keyword(s):  
Ionic Liquid ◽  
Binary Mixtures

scholarly journals The Influence of the Nature of Redox-Active Moieties on the Properties of Redox-Active Ionic Liquids and on Their Use as Electrolyte for Supercapacitors

Energies ◽  
2021 ◽  
Vol 14 (19) ◽  
pp. 6344
Author(s):  
Philipp S. Borchers ◽  
Patrick Gerlach ◽  
Yihan Liu ◽  
Martin D. Hager ◽  
Andrea Balducci ◽  
...  
Keyword(s):  
Phase Transition ◽  
Differential Scanning Calorimetry ◽  
Ionic Liquid ◽  
Ionic Liquids ◽  
Binary Mixtures ◽  
Thermal Characteristics ◽  
The Other ◽  
Scanning Calorimetry ◽  
Imidazolium Ionic Liquids ◽  
Redox Active

In this work, two new redox-active ionic liquids, one based on 2,2,6,6-tetramethylpiperidine-N-oxide and the other based on 4,4′-bipyridine, are synthesized and characterized. A ferrocene-based redox-active ionic liquid is used for referencing the results. All ionic liquids are formed via salt-metathesis from halogenate to bis(trifluoromethylsulfonyl)imide. Their fundamental thermal characteristics are assessed with differential scanning calorimetry. While the imidazolium ionic liquids show no melting point, the phase transition is well observable for the viologen-based ionic liquid. The properties of the neat redox-active ionic liquids and of binary mixtures containing these ionic liquids (0.1 m) and 1-butyl-1-methyl pyrrolidinium-bis(trifluoromethylsulfonyl)imide have been investigated. Finally, the use of these binary mixtures in combination with activated carbon-based electrodes has been considered in view of the use of these redox-active electrolytes in supercapacitors.

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