Phase Equilibrium Behavior of the Binary Systems CO2+ Nonadecane and CO2+ Soysolv and the Ternary System CO2+ Soysolv + Quaternary Ammonium Chloride Surfactant

2003 ◽  
Vol 48 (6) ◽  
pp. 1401-1406 ◽  
Author(s):  
Mohamed M. Elbaccouch ◽  
Valeriy I. Bondar ◽  
Ruben G. Carbonell ◽  
Christine S. Grant

The liquid-vapour equilibrium of the system methane-ethylene has been determined at 0, -42 , -78, -88 and -104° C over a wide range of pressures and the results are shown on a pressure-composition-temperature diagram and by a series of pressure-composition curves. The liquid-vapour equilibrium of the ternary system methane-ethane-ethylene has been determined at -104, -78 and 0° C. Values for the two binary systems methane-ethane and methane-ethylene and for the ternary system methane-ethane-ethylene are shown on a composite pressure-composition diagram.


Synlett ◽  
2019 ◽  
Vol 30 (17) ◽  
pp. 1981-1987 ◽  
Author(s):  
Michał Patrzałek ◽  
Jakub Piątkowski ◽  
Anna Kajetanowicz ◽  
Karol Grela

Easy and efficient method for preparation of all-chloro ruthenium catalysts bearing a quaternary ammonium tag was developed. The key anion metathesis reaction was made with AgCl, and the facile recycling of silver wastes was demonstrated. The developed method transforms more accessible, yet poorly characterised mixed chloro/iodo Ru complexes into valuable all-chloro catalysts, useful in aqueous metathesis. Practical utility of the developed anion metathesis reaction was demonstrated by preparation of a commercial Ru catalyst, StickyCat™, on a 5 gram scale.


2007 ◽  
Vol 62 (9) ◽  
pp. 540-544 ◽  
Author(s):  
Blanka Kubikova ◽  
Vladimir Danek ◽  
Marcelle Gaune-Escard

Formation of oxyfluoroniobium compounds in the binary systems KF-Nb2O5 and K2NbF7-Nb2O5 and in the ternary system KF-K2NbF7-Nb2O5 has been expected. Therefore the phase equilibrium and surface tension of the above systems have been determined. The three systems have only been investigated up to 20 mol% Nb2O5 because of its limited solubility. The obtained results have confirmed the formation of oxyfluoroniobium compounds.


Sign in / Sign up

Export Citation Format

Share Document