Vapor Liquid Equilibrium between (278.15 and 323.15) K and Excess Functions atT= 298.15 K for 1-Bromobutane with 2-Methyl-1-propanol or 2-Butanol

2003 ◽  
Vol 48 (2) ◽  
pp. 294-301 ◽  
Author(s):  
Santiago Martínez ◽  
Rosa Garriga ◽  
Pascual Pérez ◽  
Mariano Gracia
2021 ◽  
Vol 4 (2) ◽  
pp. 10-16
Author(s):  
S. I. Gerasymchuk ◽  
◽  
I. P. Poliuzhyn ◽  
H. V. Melnyk ◽  
Yu. P. Pavlovskyi ◽  
...  

Using a semi-empirical Wilson’s model, the vapor-liquid equilibrium in the “diethylzinc - diethyl selenide” system is described: the activity coefficients of the solution components, the separation coefficient, the excess functions of the solution (HE, GE, TSE) are calculated, and isothermal P-X diagrams are obtained. The parameters of the Wilson’s model were calculated on the basis of our data on measuring the temperature dependence for saturated vapor pressure of high-purity samples of diethylzinc, diethyl selenide and their equimolecular solution using iterations from the mathematical software package Mathsad 14. Peculiarities of intermolecular interaction in the “diethylzinc – diethyl selenide” system and the presence of a negative deviation from Raoul's law have been found. The studied system is homogeneous in the whole concentration range. The concentration dependence of the enthalpy of mixing is alternating for the researched temperature range (280-340 K).


1984 ◽  
Vol 15 (21) ◽  
Author(s):  
R. G. RUBIO ◽  
J. ARACIL ◽  
M. DIAZ PENA ◽  
J. A. R. RENUNCIO

Author(s):  
César A. García ◽  
Jessica J. Velandia ◽  
Mario A. Céspedes ◽  
Gerardo Rodríguez ◽  
Iván D. Gil

Vacuum ◽  
2021 ◽  
pp. 110245
Author(s):  
Junjie Xu ◽  
Lingxin Kong ◽  
Baoqiang Xu ◽  
Jiaqi Ren ◽  
Yifu Li ◽  
...  

AIChE Journal ◽  
1973 ◽  
Vol 19 (2) ◽  
pp. 245-251 ◽  
Author(s):  
Stanley M. Byer ◽  
Richard E. Gibbs ◽  
Hendrick C. Van Ness

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