Solubility products of the rare-earth carbonates

1986 ◽  
Vol 31 (1) ◽  
pp. 40-42 ◽  
Author(s):  
F. Henry Firsching ◽  
Javad Mohammadzadei
2015 ◽  
Vol 4 (4) ◽  
Author(s):  
Guo Lin ◽  
Libo Zhang ◽  
Shaohua Yin ◽  
Jinhui Peng ◽  
Shiwei Li ◽  
...  

AbstractThe heating behavior and effect of experimental parameters like holding time, calcination temperature and microwave power on the weight loss of the mixed rare earth carbonate using microwave heating have been studied, also characterized by X-ray diffraction, thermogravimetry-differential scanning calorimetry, scanning electron microscopy (SEM), particle analysis and Fourier transform infrared (FT-IR). The results show the following: rare earth oxides are obtained at 850°C for holding 1 h; FT-IR analysis indicates that the vibration absorption peak of carbonate disappears after calcination using microwave, confirming the feasibility of microwave calcination for the rare earth carbonates; SEM shows that the rare earth oxides have the characteristics of better and finer particles, have better dispersion and have surface that is more loose and porous than that of products using conventional calcination; particle analysis indicates that average size (D


1981 ◽  
Vol 26 (2) ◽  
pp. 116-118
Author(s):  
F. Henry Firsching ◽  
Robert C. Cuca

Materials ◽  
2019 ◽  
Vol 12 (13) ◽  
pp. 2062 ◽  
Author(s):  
Luca Spiridigliozzi ◽  
Claudio Ferone ◽  
Raffaele Cioffi ◽  
Mauro Bortolotti ◽  
Gianfranco Dell’Agli

The rare-earth carbonates represent a class of materials with great research interest owing to their intrinsic properties and because they can be used as template materials for the formation of other rare earth phases, particularly of rare-earth oxides. However, most of the literature is focused on the synthesis and characterization of hydroxycarbonates. Conversely, in the present study we have synthesized both rare-earth carbonates—with the chemical formula RE2(CO3)3·2-3H2O, in which RE represents a generic rare-earth element, and a tengerite-type structure with a peculiar morphology—and rare-earth hydroxycarbonates with the chemical formula RECO3OH, by hydrothermal treatment at low temperature (120 °C), using metal nitrates and ammonium carbonates as raw materials, and without using any additive or template. We found that the nature of the rare-earth used plays a crucial role in relation to the formed phases, as predicted by the contraction law of lanthanides. In particular, the hydrothermal synthesis of rare-earth carbonates with a tengerite-type structure was obtained for the lanthanides from neodymium to erbium. A possible explanation of the different behaviors of lighter and heavier rare-earths is given.


1962 ◽  
Vol 18 (4) ◽  
pp. 1127-1153
Author(s):  
V FASSEL ◽  
R CURRY ◽  
R KNISELEY

1963 ◽  
Vol 79 (2) ◽  
pp. 263-293 ◽  
Author(s):  
E.M. Savitskii ◽  
V.F. Terekhova ◽  
O.P. Naumkin

2018 ◽  
Vol 17 (8) ◽  
pp. 2001-2009
Author(s):  
Tatjana Juzsakova ◽  
Akos Redey ◽  
Le Phuoc Cuong ◽  
Zsofia Kovacs ◽  
Tamas Frater ◽  
...  

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