Vapor-liquid equilibriums of acetylacetone-organic solvent systems

1981 ◽  
Vol 26 (3) ◽  
pp. 287-293 ◽  
Author(s):  
Mikio Inoue ◽  
Yasuhiko Arai ◽  
Shozaburo Saito ◽  
Nobuo Suzuki
Keyword(s):  
Organic Solvent ◽  
Solvent Systems ◽  
Vapor Liquid

scholarly journals Upgrading Components from Organic Solvent Systems using NF Membranes

2012 ◽  
Vol 44 ◽  
pp. 238-240
Author(s):  
F.P. Cuperus ◽  
I.M. Wienk
Keyword(s):  
Organic Solvent ◽  
Solvent Systems

The Effect of Solvent on the Seebeck Coefficient and Thermocell Performance of Cobalt Bipyridyl and Iron Ferri/Ferrocyanide Redox Couples

2019 ◽  
Vol 72 (9) ◽  
pp. 709 ◽  
Author(s):  
Abuzar Taheri ◽  
Douglas R. MacFarlane ◽  
Cristina Pozo-Gonzalo ◽  
Jennifer M. Pringle
Keyword(s):  
Organic Solvent ◽  
Seebeck Coefficient ◽  
Mixed Solvent ◽  
Waste Heat ◽  
Redox Couple ◽  
Seebeck Coefficients ◽  
Effect Of Solvent ◽  
Redox Couples ◽  
Ligand Interactions ◽  
Solvent Systems

The conversion of thermal energy to electricity using thermoelectrochemical cells (thermocells) is a developing approach to harvesting waste heat. The performance of a thermocell is highly dependent on the solvent used in the electrolyte, but the interplay of the various solvent effects is not yet well understood. Here, using the redox couples [Co(bpy)3][BF4]2/3 (bpy=2,2′-bipyridyl) and (Et4N)3/(NH4)4Fe(CN)6, which have been designed to allow dissolution in different solvent systems (aqueous, non-aqueous, and mixed solvent), the effect of solvent on the Seebeck coefficient (Se) and cell performance was studied. The highest Se for a cobalt-based redox couple measured thus far is reported. Different trends in the Seebeck coefficients of the two redox couples as a function of the ratio of organic solvent to water were observed. The cobalt redox couple produced a more positive Se in organic solvent than in water, whereas addition of water to organic solvent resulted in a more negative Se for Fe(CN)6 3−/4−. UV-vis and IR investigations of the redox couples indicate that Se is affected by changes in solvent–ligand interactions in the different solvent systems.

Measurements of liquid–liquid equilibria of water+ε-caprolactam+electrolyte+organic solvent systems

1999 ◽  
Vol 158-160 ◽  
pp. 939-947 ◽  
Author(s):  
M Wijtkamp ◽  
G.H van Bochove ◽  
Th.W de Loos ◽  
S.H Niemann
Keyword(s):  
Organic Solvent ◽  
Solvent Systems
Sign in / Sign up

Export Citation Format

Share Document