Densities and Excess Molar Volumes of Binary Mixtures Containing Propylene Carbonate + 10 Chlorohydrocarbons at 298.15 K and Atmospheric Pressure

1995 ◽  
Vol 40 (6) ◽  
pp. 1184-1187 ◽  
Author(s):  
Fabio Comelli ◽  
Romolo Francesconi
Keyword(s):  
Binary Mixtures ◽  
Propylene Carbonate ◽  
Atmospheric Pressure ◽  
Excess Molar Volumes ◽  
Molar Volumes

Intermolecular Interaction for Binary Mixtures of Propylene Carbonate with Acetonitrile, Dimethyl Carbonate, Diethyl Carbonate at Different Temperatures: Density and Viscosity

2017 ◽  
Vol 232 (1) ◽  
Author(s):  
Wei Song ◽  
Hai Zhang ◽  
Zhenyu Yang ◽  
Juan Wang ◽  
Zishuang Yue ◽  
...  
Keyword(s):  
Intermolecular Interaction ◽  
Binary Mixtures ◽  
Propylene Carbonate ◽  
Atmospheric Pressure ◽  
Dimethyl Carbonate ◽  
Excess Molar Volumes ◽  
Diethyl Carbonate ◽  
Molar Volumes ◽  
Different Temperatures

AbstractIn this work, the experimental densities and viscosities have been determined for (propylene carbonate+acetonitrile, or dimethyl carbonate, or diethyl carbonate) binary mixtures over the whole concentration range at temperatures (293.15–333.15 K) and the atmospheric pressure. Excess molar volumes (

Excess Molar Volumes of Butyl Acetate+an n-Alkanol at 298.15 K

1985 ◽  
Vol 38 (10) ◽  
pp. 1435 ◽  
Author(s):  
J Ortega ◽  
MI Paz-Andrade ◽  
E Rodriguez-Nunez ◽  
L Romani
Keyword(s):  
Binary Mixtures ◽  
Atmospheric Pressure ◽  
Butyl Acetate ◽  
Composition Range ◽  
Excess Molar Volumes ◽  
Hydrocarbon Chain ◽  
Excess Volumes ◽  
Entire Composition Range ◽  
Specific Interactions ◽  
Molar Volumes

Excess molar volumes VEm at 298.15 K and atmospheric pressure were calculated over the entire composition range from densities measured with a vibrating-tube digital densimeter for the binary mixtures butyl acetate + methanol, + ethanol, + propan-1-ol, + butan-1-ol, + pentan-1- ol, + hexan-1-ol, + heptan-1-ol, + octan-1-ol, + nonan-1-ol and + decan-1-ol. The excess volumes are positive over the entire composition range for these mixtures except the system butyl acetate + methanol, for which all VEm values are negative. The excess volumes show a consistent trend towards more positive values as the length of the hydrocarbon chain of the alkanol increases. The results suggest the presence of specific interactions.

Excess molar volumes and viscosities of binary mixtures of triethylene glycol dimethyl ether (triglyme) with chloroalkanes at 298.15 K

2000 ◽  
Vol 78 (4) ◽  
pp. 444-448
Author(s):  
Amalendu Pal ◽  
Gurcharan Dass
Keyword(s):  
Binary Mixtures ◽  
Dimethyl Ether ◽  
Atmospheric Pressure ◽  
Excess Volume ◽  
Excess Molar Volumes ◽  
Triethylene Glycol ◽  
Viscosity Deviation ◽  
Molar Volumes ◽  
Glycol Dimethyl Ether ◽  
Volume Viscosity

Excess molar volumes (VEm) and viscosities (η) for mixtures of triethylene glycol dimethyl ether + dichloromethane, + trichloromethane, and + tetrachloromethane have been determined at 298.15 K and atmospheric pressure over the whole concentration range. From the experimental results, deviations in viscosities (Δ ln η) have been calculated. These properties were fitted to the polynomial relations to obtain the coefficients and the standard deviations. The results have been analysed in terms of molecular interactions between components.Key words: experiments, data, excess volume, viscosity deviation, binary mixtures.

Sign in / Sign up

Export Citation Format

Share Document