Formation of Protonated ortho-Quinonimide from ortho-Iodoaniline in the Gas Phase by a Molecular-Oxygen-Mediated, ortho-Isomer-Specific Fragmentation Mechanism

2020 ◽  
Vol 31 (4) ◽  
pp. 864-872
Author(s):  
Ramu Errabelli ◽  
Zhaoyu Zheng ◽  
Athula B. Attygalle
2017 ◽  
Vol 43 (12) ◽  
pp. 7055-7071 ◽  
Author(s):  
Shengqiang Xu ◽  
Qingming Huang ◽  
Yanting Xu ◽  
Zhuoliang Ye ◽  
Xiaohui Chen

2012 ◽  
Vol 179 ◽  
pp. 285-294 ◽  
Author(s):  
Van-Huy Nguyen ◽  
Hsiang-Yu Chan ◽  
Jeffrey C.S. Wu ◽  
Hsunling Bai

2003 ◽  
Vol 5 (5) ◽  
pp. 956-965 ◽  
Author(s):  
Rei Hamada ◽  
Yusuke Shibata ◽  
Satoru Nishiyama ◽  
Shigeru Tsuruya

1972 ◽  
Vol 45 (2) ◽  
pp. 423-436 ◽  
Author(s):  
M. L. Kaplan ◽  
P. G. Kelleher

Abstract Excited molecular oxygen in its singlet delta (1Δg) state can be made chemically in homogeneous solution and in the gas-phase by the electrodeless discharge of ground state oxygen. Both techniques have been used to perform oxidations of polydiene systems. Solutions of high cis, trans, and vinyl polybutadienes have been treated with singlet oxygen produced in situ. Only the high cis and high trans were oxidized, apparently by different mechanisms. Squalene, a model for polyisoprene, has been oxidized in solution and the initially formed hydroperoxides reduced and analyzed and found identical to the product from a photosensitized oxidation. Cis-polybutadiene films were treated with gas-phase singlet oxygen and the extent of surface oxidation was monitored spectroscopically and chemically.


2013 ◽  
Vol 117 (41) ◽  
pp. 10736-10745 ◽  
Author(s):  
L. Onel ◽  
L. Thonger ◽  
M. A. Blitz ◽  
P. W. Seakins ◽  
A. J. C. Bunkan ◽  
...  

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