scholarly journals Generation of Multiply Charged Protein Anions from Multiply Charged Protein Cations via Gas-Phase Ion/Ion Reactions

2020 ◽  
Vol 31 (7) ◽  
pp. 1509-1517
Author(s):  
Hsi-Chun Chao ◽  
Mack Shih ◽  
Scott A. McLuckey
2008 ◽  
Vol 19 (2) ◽  
pp. 281-293 ◽  
Author(s):  
Christopher K. Barlow ◽  
Brittany D. M. Hodges ◽  
Yu Xia ◽  
Richard A. J. O’Hair ◽  
Scott A. McLuckey

2020 ◽  
Author(s):  
Oisin Shiels ◽  
P. D. Kelly ◽  
Cameron C. Bright ◽  
Berwyck L. J. Poad ◽  
Stephen Blanksby ◽  
...  

<div> <div> <div> <p>A key step in gas-phase polycyclic aromatic hydrocarbon (PAH) formation involves the addition of acetylene (or other alkyne) to σ-type aromatic radicals, with successive additions yielding more complex PAHs. A similar process can happen for N- containing aromatics. In cold diffuse environments, such as the interstellar medium, rates of radical addition may be enhanced when the σ-type radical is charged. This paper investigates the gas-phase ion-molecule reactions of acetylene with nine aromatic distonic σ-type radical cations derived from pyridinium (Pyr), anilinium (Anl) and benzonitrilium (Bzn) ions. Three isomers are studied in each case (radical sites at the ortho, meta and para positions). Using a room temperature ion trap, second-order rate coefficients, product branching ratios and reaction efficiencies are reported. </p> </div> </div> </div>


Author(s):  
Ying Zhao ◽  
Emma Rostal Sørensen ◽  
Thomas Toft Lindkvist ◽  
Christina Kjær ◽  
Mogens Brøndsted Nielsen ◽  
...  
Keyword(s):  

Author(s):  
MingMin Zhong ◽  
Hong Fang ◽  
Deepika Deepika ◽  
Purusottam Jena

Stabilization of multiply-charged atomic clusters in the gas phase has been a topic of great interest not only because of their potential applications as weakly-coordinating anions, but also for their...


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