scholarly journals Redox-Inactive Metal Cations Modulate the Reduction Potential of the Uranyl Ion in Macrocyclic Complexes

2020 ◽  
Vol 142 (6) ◽  
pp. 3032-3041 ◽  
Author(s):  
Amit Kumar ◽  
Davide Lionetti ◽  
Victor W. Day ◽  
James D. Blakemore
1980 ◽  
Vol 63 (3) ◽  
pp. 668-673 ◽  
Author(s):  
Alexander I. Popov ◽  
Alfred J. Smetana ◽  
Jean-Pierre Kintzinger ◽  
Thi Thanh-Tâam Nguyêen

2006 ◽  
Vol 128 (30) ◽  
pp. 9610-9611 ◽  
Author(s):  
Polly L. Arnold ◽  
Dipti Patel ◽  
Alexander J. Blake ◽  
Claire Wilson ◽  
Jason B. Love
Keyword(s):  

2015 ◽  
Vol 2015 ◽  
pp. 1-9
Author(s):  
Marcelo Carpes Nunes ◽  
Marcos Antonio Ribeiro ◽  
Fábio Souza Nunes

The polynuclear complexes [Mo3O8(tidf)]·dmso·2H2O (1) and [{Cu2(tidf)}2(μ-Mo8O24)] (2) (tidf2−is a symmetrical tetraiminodiphenolate Robson-type macrocyclic ligand) were prepared from equimolar combinations of [Mg2(tidf)](NO3)2·4H2O, [MoO2Cl2(dmso)2] (for1) and complex1and Cu(ClO4)2·4H2O (for2) in acetonitrile. Molecular structures of both complexes were determined and showed atypical modes of coordination. A significant observation was the remarkable flexibility of the macrocycle ligand that effectively accommodated the steric demands of metal cations and the packing forces and showed a unique mode of coordination. Spectroscopic (UV-vis and FTIR) and redox properties are discussed.


2015 ◽  
Vol 82 (5) ◽  
pp. 839-841
Author(s):  
D. S. Umreiko ◽  
N. P. Vileishikova ◽  
A. P. Zajogin ◽  
A. I. Komyak

1985 ◽  
Vol 110 (1) ◽  
pp. L1-L2 ◽  
Author(s):  
L. De Cola ◽  
D.L. Smailes ◽  
L.M. Vallarino

1980 ◽  
Vol 11 (33) ◽  
Author(s):  
A. I. POPOV ◽  
A. J. SMETANA ◽  
J.-P. KINTZINGER ◽  
NGUYEN THI THANH-TAM NGUYEN THI THANH-TAM

1981 ◽  
Vol 31 (1) ◽  
pp. 597-601 ◽  
Author(s):  
Karim Farag ◽  
Francis Perineau ◽  
Antoine Gaset ◽  
Jacques Molinier

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