scholarly journals Correction to “Solid State Multicolor Emission in Substitutional Solid Solutions of Metal–Organic Frameworks”

2019 ◽  
Vol 141 (39) ◽  
pp. 15718-15718
Author(s):  
Wesley J. Newsome ◽  
Suliman Ayad ◽  
Jesus Cordova ◽  
Eric W. Reinheimer ◽  
Andres D. Campiglia ◽  
...  
Keyword(s):  
Solid State ◽  
Solid Solutions ◽  
Metal Organic Frameworks ◽  
Substitutional Solid Solutions ◽  
Metal Organic

Solid State Multicolor Emission in Substitutional Solid Solutions of Metal–Organic Frameworks

2019 ◽  
Vol 141 (28) ◽  
pp. 11298-11303 ◽  
Author(s):  
Wesley J. Newsome ◽  
Suliman Ayad ◽  
Jesus Cordova ◽  
Eric W. Reinheimer ◽  
Andres D. Campiglia ◽  
...  
Keyword(s):  
Solid State ◽  
Solid Solutions ◽  
Metal Organic Frameworks ◽  
Substitutional Solid Solutions ◽  
Metal Organic

Tunable Solid-State Multicolor Emission in Substitutional Solid Solutions of Metal-Organic Frameworks

2019 ◽  
Author(s):  
Wesley Newsome ◽  
Suliman Ayad ◽  
Jesus Cordova ◽  
Eric Reinheimer ◽  
Andres Campiglia ◽  
...  
Keyword(s):  
Solid State ◽  
Solid Solutions ◽  
Hydrolytic Stability ◽  
Metal Organic Frameworks ◽  
Substitutional Solid Solution ◽  
Quantum Yields ◽  
Ambient Conditions ◽  
Excited State Proton Transfer ◽  
Substitutional Solid Solutions ◽  
Metal Organic

Realization of organic-based substitutional solid solutions will facilitate the preparation of solid-state materials with properties that arise from phenomena only displayed by molecules in solution. We demonstrate that multivariate metal-organic frameworks, MOFs, exhibit organic-based substitutional solid solution behavior by tuning their fluorescence, dictated exclusively by predetermined ratios of multivariate organic links. By combining non-fluorescent links with dilute mixtures of red, green, and blue fluorescent links we prepared zirconia-type MOFs that exhibit features of solution-like fluorescence. Our study found that MOFs with fluorophore link concentration of around 1 %mol exhibit fluorescence with decreased inner filtering demonstrated by changes in spectra profiles, quantum yields, and lifetime dynamics expected for excited state proton transfer emitters. Our findings enabled us to prepare organic-based substitutional solid solutions with tunable chromaticity. These materials emit multicolor and white light with high quantum yields, long shelf life, and superb hydrolytic stability at ambient conditions.

Tunable Solid-State Multicolor Emission in Substitutional Solid Solutions of Metal-Organic Frameworks

2019 ◽  
Author(s):  
Wesley Newsome ◽  
Suliman Ayad ◽  
Jesus Cordova ◽  
Eric Reinheimer ◽  
Andres Campiglia ◽  
...  
Keyword(s):  
Solid State ◽  
Solid Solutions ◽  
Hydrolytic Stability ◽  
Metal Organic Frameworks ◽  
Substitutional Solid Solution ◽  
Quantum Yields ◽  
Ambient Conditions ◽  
Excited State Proton Transfer ◽  
Substitutional Solid Solutions ◽  
Metal Organic

Realization of organic-based substitutional solid solutions will facilitate the preparation of solid-state materials with properties that arise from phenomena only displayed by molecules in solution. We demonstrate that multivariate metal-organic frameworks, MOFs, exhibit organic-based substitutional solid solution behavior by tuning their fluorescence, dictated exclusively by predetermined ratios of multivariate organic links. By combining non-fluorescent links with dilute mixtures of red, green, and blue fluorescent links we prepared zirconia-type MOFs that exhibit features of solution-like fluorescence. Our study found that MOFs with fluorophore link concentration of around 1 %mol exhibit fluorescence with decreased inner filtering demonstrated by changes in spectra profiles, quantum yields, and lifetime dynamics expected for excited state proton transfer emitters. Our findings enabled us to prepare organic-based substitutional solid solutions with tunable chromaticity. These materials emit multicolor and white light with high quantum yields, long shelf life, and superb hydrolytic stability at ambient conditions.

Phase selectivity and tunable photophysical nature of rare earth metal–organic frameworks of EuxY1−x-PTC (H3PTC = 2,4,6-pyridine tricarboxylic acid; x = 0–1)

2020 ◽  
Vol 49 (42) ◽  
pp. 14985-14994
Author(s):  
Xu-Sheng Gao ◽  
Mei-Juan Ding ◽  
Jin Zhang ◽  
Li-Duo Zhao ◽  
Xiao-Ming Ren
Keyword(s):  
Rare Earth ◽  
Solid Solutions ◽  
Rare Earth Metal ◽  
Metal Organic Frameworks ◽  
Earth Metal ◽  
Tricarboxylic Acid ◽  
Excitation Wavelength ◽  
Metal Organic ◽  
Phase Selectivity

All solid solutions (EuxY1−x-PTC, x = 0.013–0.82) are isomorphic to Eu-PTC, but different from Y-PTC, and show phase selectivity as well as excitation wavelength dependent emission.

Rational strategies for proton-conductive metal–organic frameworks

2021 ◽  
Author(s):  
Dae-Woon Lim ◽  
Hiroshi Kitagawa
Keyword(s):  
Solid State ◽  
Potential Application ◽  
High Performance ◽  
Metal Organic Frameworks ◽  
Metal Organic ◽  
Solid State Electrolytes

Since the transition of energy platforms, the proton-conductive metal–organic frameworks (MOFs) exhibiting high performance have been extensively investigated with rational strategies for their potential application in solid-state electrolytes.

Photoactive Zr and Ti Metal‐Organic‐Frameworks for solid‐state solar cells

ChemPhysChem ◽  
2021 ◽  
Author(s):  
Arianna Melillo ◽  
Rocio Garcia ◽  
Sergio Navalon ◽  
Pedro Atienzar ◽  
Belen Ferrer ◽  
...  
Keyword(s):  
Solar Cells ◽  
Solid State ◽  
Metal Organic Frameworks ◽  
Metal Organic

scholarly journals Mechanochemical and solvent-free assembly of zirconium-based metal–organic frameworks

2016 ◽  
Vol 52 (10) ◽  
pp. 2133-2136 ◽  
Author(s):  
Krunoslav Užarević ◽  
Timothy C. Wang ◽  
Su-Young Moon ◽  
Athena M. Fidelli ◽  
Joseph T. Hupp ◽  
...  
Keyword(s):  
Solid State ◽  
High Temperatures ◽  
Self Assembly ◽  
Metal Organic Frameworks ◽  
Accelerated Aging ◽  
Solvent Free ◽  
Catalytically Active ◽  
Metal Organic ◽  
Strong Acids ◽  
Zirconium Metal

Mechanochemistry and accelerated aging are new routes to zirconium metal–organic frameworks, yielding UiO-66 and catalytically active UiO-66-NH2 accessible on the gram scale through mild solid-state self-assembly, without strong acids, high temperatures or excess reactants.

Phosphorization Engineering on Metal–Organic Frameworks for Quasi‐Solid‐State Asymmetry Supercapacitors

Small ◽  
2020 ◽  
pp. 2007062
Author(s):  
Xijun Wei ◽  
Yingze Song ◽  
Lixian Song ◽  
Xu Dong Liu ◽  
Yanhong Li ◽  
...  
Keyword(s):  
Solid State ◽  
Metal Organic Frameworks ◽  
Metal Organic
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