scholarly journals Reactivity Profiles of Diazo Amides, Esters, and Ketones in Transition-Metal-Free C–H Insertion Reactions

2019 ◽  
Vol 141 (8) ◽  
pp. 3558-3565 ◽  
Author(s):  
Sarah E. Cleary ◽  
Xin Li ◽  
Li-Cheng Yang ◽  
K. N. Houk ◽  
Xin Hong ◽  
...  
Keyword(s):  
Transition Metal ◽  
Insertion Reactions ◽  
Metal Free

scholarly journals The involvement of the trisulfur radical anion in electron-catalyzed sulfur insertion reactions: facile synthesis of benzothiazine derivatives under transition metal-free conditions

2016 ◽  
Vol 7 (7) ◽  
pp. 4067-4072 ◽  
Author(s):  
Zheng-Yang Gu ◽  
Jia-Jia Cao ◽  
Shun-Yi Wang ◽  
Shun-Jun Ji
Keyword(s):  
Transition Metal ◽  
Radical Anion ◽  
Insertion Reaction ◽  
Insertion Reactions ◽  
Facile Synthesis ◽  
Metal Free ◽  
Practical Synthesis

An efficient and practical synthesis of benzothiazine by K2S initiated sulfur insertion reaction with enaminones via electron catalysis is developed.

Transition-metal-free insertion reactions of alkynes into the C–N σ-bonds of imides: synthesis of substituted enamides or chromones

2018 ◽  
Vol 54 (48) ◽  
pp. 6192-6195 ◽  
Author(s):  
Zhong Zheng ◽  
Ye Wang ◽  
Murong Xu ◽  
Lingkai Kong ◽  
Mengdan Wang ◽  
...  
Keyword(s):  
Transition Metal ◽  
Selective Synthesis ◽  
Insertion Reactions ◽  
Metal Free

Transition-metal-free insertion of ynones into the C–N σ-bonds of imides for the chemo-selective synthesis of chromones or enamides.

Transition-metal-free catalytic hydroboration reduction of amides to amines

2020 ◽  
Vol 7 (21) ◽  
pp. 3515-3520
Author(s):  
Wubing Yao ◽  
Jiali Wang ◽  
Aiguo Zhong ◽  
Shiliang Wang ◽  
Yinlin Shao
Keyword(s):  
Transition Metal ◽  
Selective Catalytic Reduction ◽  
Catalytic Reduction ◽  
Value Added ◽  
Metal Free

The selective catalytic reduction of amides to value-added amine products is a desirable but challenging transformation.

Deaminative carbonylative thioesterification of activated alkylamines with thiophenols under transition-metal-free conditions

2021 ◽  
Author(s):  
Fengqian Zhao ◽  
Xiao-Feng Wu
Keyword(s):  
Free Radical ◽  
Transition Metal ◽  
Metal Free

A transition-metal-free radical carbonylation of activated alkylamines with thiophenols has been successfully developed. Various thioesters were selectively produced with moderate to good yields.

Regioselective C3-H Trifluoromethylation of 2H-Indazole Under Transition-Metal-Free Photoredox Catalysis

2019 ◽  
Author(s):  
Arumugavel Murugan ◽  
Venkata Nagarjuna Babu ◽  
Nagaraj Sabarinathan ◽  
Sharada Duddu. S
Keyword(s):  
Transition Metal ◽  
Visible Light ◽  
Practical Approach ◽  
Hypervalent Iodine ◽  
Radical Mechanism ◽  
Photoredox Catalysis ◽  
Metal Free

Here we report a visible-light-promoted metal-free regioselective C3-H trifluoromehtylation reaction that proceeds via radical mechanism and which supported by control experiments. The combination of photoredox catalysis and hypervalent iodine reagent provides a practical approach for the present trifluoromethylation reaction and synthesis of a library of trifluoromethylated indazoles.

Selective Oxidation of Alcohols Catalyzed by a Transition Metal-Free System of NHPI/DDQ/NaNO2

2011 ◽  
Vol 32 (1) ◽  
pp. 118-122 ◽  
Author(s):  
Lipeng ZHOU ◽  
Chaofeng ZHANG ◽  
Tao FANG ◽  
Bingbing ZHANG ◽  
Ying WANG ◽  
...  
Keyword(s):  
Transition Metal ◽  
Selective Oxidation ◽  
Free System ◽  
Metal Free ◽  
Oxidation Of Alcohols

Defect engineering and characterization of active sites for efficient electrocatalysis

Nanoscale ◽  
2021 ◽  
Vol 13 (6) ◽  
pp. 3327-3345
Author(s):  
Xuecheng Yan ◽  
Linzhou Zhuang ◽  
Zhonghua Zhu ◽  
Xiangdong Yao
Keyword(s):  
Transition Metal ◽  
Active Sites ◽  
Defect Engineering ◽  
Metal Free

This review highlights recent advancements in defect engineering and characterization of both metal-free carbons and transition metal-based electrocatalysts.

Transition metal free, green and facile halogenation of ketene dithioacetals using a KX–oxidant system

2021 ◽  
Author(s):  
Vishakha Rai ◽  
Ganesh Shivayogappa Sorabad ◽  
Mahagundappa Rachappa Maddani
Keyword(s):  
Transition Metal ◽  
Ambient Temperature ◽  
Metal Free ◽  
Ketene Dithioacetals ◽  
System P ◽  
Oxidative Halogenation ◽  
Potassium Halide

A facile oxidative halogenation of α-oxo ketene dithioacetals is achieved by using a potassium halide and an oxidant combination under transition metal free conditions at ambient temperature.

Highly chemoselective deoxygenation of N-heterocyclic N-oxides under transition metal-free conditions

2021 ◽  
Vol 19 (16) ◽  
pp. 3735-3742
Author(s):  
Se Hyun Kim ◽  
Ju Hyeon An ◽  
Jun Hee Lee
Keyword(s):  
Transition Metal ◽  
Visible Light ◽  
Eosin Y ◽  
Metal Free ◽  
Simple Protocol

Here, we provide an operationally simple protocol for the highly chemoselective deoxygenation of various functionalized N-heterocyclic N-oxides under visible light-mediated photoredox conditions with Na2-eosin Y as an organophotocatalyst.

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