scholarly journals Tunable Mixed-Valence Doping toward Record Electrical Conductivity in a Three-Dimensional Metal–Organic Framework

2018 ◽  
Vol 140 (24) ◽  
pp. 7411-7414 ◽  
Author(s):  
Lilia S. Xie ◽  
Lei Sun ◽  
Ruomeng Wan ◽  
Sarah S. Park ◽  
Jordan A. DeGayner ◽  
...  
Keyword(s):  
Electrical Conductivity ◽  
Metal Organic Framework ◽  
Mixed Valence ◽  
Three Dimensional ◽  
Metal Organic ◽  
Organic Framework

scholarly journals Switchable electrical conductivity in a three-dimensional metal–organic framework via reversible ligand n-doping

2020 ◽  
Vol 11 (5) ◽  
pp. 1342-1346 ◽  
Author(s):  
Hanna C. Wentz ◽  
Grigorii Skorupskii ◽  
Ana B. Bonfim ◽  
Jenna L. Mancuso ◽  
Christopher H. Hendon ◽  
...  
Keyword(s):  
Electrical Conductivity ◽  
Metal Organic Framework ◽  
Three Dimensional ◽  
Redox Active Ligands ◽  
Redox Active ◽  
N Doping ◽  
Metal Organic ◽  
Organic Framework

Redox-active ligands are used to reversibly tune electrical conductivity in a porous 3D metal–organic framework (MOF).

scholarly journals High Electrical Conductivity in Three-Dimensional Porphyrin-Phosphonate Metal Organic-Frameworks

2021 ◽  
Author(s):  
Yunus Zorlu ◽  
Patrik Tholen ◽  
Mehmet Menaf Ayhan ◽  
Ceyda Bayraktar ◽  
Gabriel Hanna ◽  
...  
Keyword(s):  
Electrical Conductivity ◽  
Low Cost ◽  
Metal Organic Framework ◽  
Three Dimensional ◽  
High Yield ◽  
Electrically Conductive ◽  
Design And Synthesis ◽  
Metal Organic ◽  
Indirect Band Gap ◽  
Organic Framework

<p>Herein, we report the design and synthesis of a highly electrically conductive and microporous three-dimensional zinc-phosphonate metal-organic framework [Zn(Cu-<i>p</i>-H<sub>4</sub>TPPA)] ⋅2 (CH<sub>3</sub>)<sub>2</sub>NH<sub>2</sub><sup>+</sup> (designated as GTUB3), constructed using the 5,10,15,20‐tetrakis [<i>p</i>‐phenylphosphonic acid] porphyrin (<i>p</i>-H<sub>8</sub>TPPA) organic linker. GTUB3 has an indirect band gap of 1.64 eV and a high average electrical conductivity of<b> </b>4 S/m, making it a rare example of an electrically conductive zinc metal-organic framework. The N<sub>2</sub>-accessible geometric surface area of GTUB3, as predicted by molecular simulations, is 671 m<sup>2</sup>/g. Owing to its simple, high-yield synthesis at low temperatures, porosity, and electrical conductivity, GTUB3 may be used as a low-cost electrode material in next generation phosphonate-supercapacitors. </p>

scholarly journals High Electrical Conductivity in Three-Dimensional Porphyrin-Phosphonate Metal Organic-Frameworks

2021 ◽  
Author(s):  
Yunus Zorlu ◽  
Patrik Tholen ◽  
Mehmet Menaf Ayhan ◽  
Ceyda Bayraktar ◽  
Gabriel Hanna ◽  
...  
Keyword(s):  
Electrical Conductivity ◽  
Low Cost ◽  
Metal Organic Framework ◽  
Three Dimensional ◽  
High Yield ◽  
Electrically Conductive ◽  
Design And Synthesis ◽  
Metal Organic ◽  
Indirect Band Gap ◽  
Organic Framework

<p>Herein, we report the design and synthesis of a highly electrically conductive and microporous three-dimensional zinc-phosphonate metal-organic framework [Zn(Cu-<i>p</i>-H<sub>4</sub>TPPA)] ⋅2 (CH<sub>3</sub>)<sub>2</sub>NH<sub>2</sub><sup>+</sup> (designated as GTUB3), constructed using the 5,10,15,20‐tetrakis [<i>p</i>‐phenylphosphonic acid] porphyrin (<i>p</i>-H<sub>8</sub>TPPA) organic linker. GTUB3 has an indirect band gap of 1.64 eV and a high average electrical conductivity of<b> </b>4 S/m, making it a rare example of an electrically conductive zinc metal-organic framework. The N<sub>2</sub>-accessible geometric surface area of GTUB3, as predicted by molecular simulations, is 671 m<sup>2</sup>/g. Owing to its simple, high-yield synthesis at low temperatures, porosity, and electrical conductivity, GTUB3 may be used as a low-cost electrode material in next generation phosphonate-supercapacitors. </p>

Three-dimensional hierarchical C-Co-N/Se derived from metal-organic framework as superior cathode for Li-Se batteries

2017 ◽  
Vol 363 ◽  
pp. 103-109 ◽  
Author(s):  
Jiarui He ◽  
Weiqiang Lv ◽  
Yuanfu Chen ◽  
Jie Xiong ◽  
Kechun Wen ◽  
...  
Keyword(s):  
Metal Organic Framework ◽  
Three Dimensional ◽  
Metal Organic ◽  
Organic Framework

Electron transitions in a Ce(iii)-catecholate metal–organic framework

2022 ◽  
Author(s):  
Julia G. Knapp ◽  
Debmalya Ray ◽  
Paul B. Calio ◽  
Megan C. Wasson ◽  
Thais R. Scott ◽  
...  
Keyword(s):  
Metal Organic Framework ◽  
Three Dimensional ◽  
Electron Transitions ◽  
Metal Organic ◽  
Organic Framework

Competitive electron transitions are present in a rare three-dimensional Ce(iii)-catecholate metal–organic framework.

Li-based MOF-derived multifunctional PEO polymer solid-state electrolyte for lithium energy storage

2022 ◽  
Author(s):  
Xiang Han ◽  
Tiantian Wu ◽  
Lanhui Gu ◽  
Dian Tian
Keyword(s):  
Energy Storage ◽  
Solid State ◽  
Metal Organic Framework ◽  
Three Dimensional ◽  
Isophthalic Acid ◽  
Solid State Electrolyte ◽  
Metal Organic ◽  
Solvothermal Conditions ◽  
Organic Framework

A three-dimensional (3D) metal-organic framework containing Li-oxygen clusters, namely {[Li2(IPA)]·DMF}n (1) (H2IPA = isophthalic acid), has been constructed under solvothermal conditions. The Li-based MOF can be applied to lithium energy...

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