scholarly journals Endo and Exo Diels–Alder Adducts: Temperature-Tunable Building Blocks for Selective Chemical Functionalization

2018 ◽  
Vol 140 (15) ◽  
pp. 5009-5013 ◽  
Author(s):  
Emre H. Discekici ◽  
Andre H. St. Amant ◽  
Shay N. Nguyen ◽  
In-Hwan Lee ◽  
Craig J. Hawker ◽  
...  
Keyword(s):  
Building Blocks ◽  
Diels Alder ◽  
Chemical Functionalization ◽  
Selective Chemical

scholarly journals Furoic Acid and Derivatives as Atypical Dienes in Diels-Alder Reactions

2021 ◽  
Author(s):  
Razvan Cioc ◽  
Tom Smak ◽  
Marc Crockatt ◽  
Jan Kees Van der Waal ◽  
Pieter C A Bruijnincx
Keyword(s):  
Green Chemistry ◽  
Cycloaddition Reaction ◽  
Building Blocks ◽  
Diels Alder ◽  
Furoic Acid

The furan Diels-Alder (DA) cycloaddition reaction has become an important tool in green chemistry, being central to the sustainable synthesis of many chemical building blocks. The restriction to electron-rich furans...

scholarly journals Synthesis of fluorinated δ-lactams via cycloisomerization of gem-difluoropropargyl amides

2010 ◽  
Vol 6 ◽  
Author(s):  
Satoru Arimitsu ◽  
Gerald B Hammond
Keyword(s):  
Building Blocks ◽  
Alder Reaction ◽  
Diels Alder ◽  
Tandem Reaction ◽  
Enyne Metathesis ◽  
Metathesis Reaction ◽  
Ring Closing Metathesis ◽  
Diels Alder Reaction

gem-Difluoro-1,7-enyne amides are suitable building blocks for the synthesis of difluorodihydropyridinones via a ring-closing metathesis reaction, and of 4,4-difluoro-3-oxoisoquinolines through a ring-closing metathesis–enyne metathesis tandem reaction. These products, in turn, undergo a Diels–Alder reaction to yield heterotricyclic systems in moderate to good yields.

scholarly journals An aza-Diels–Alder route to quinoline-based unnatural amino acids and polypeptide surrogates

RSC Advances ◽  
2021 ◽  
Vol 11 (23) ◽  
pp. 14132-14139
Author(s):  
M. J. Umerani ◽  
H. Yang ◽  
P. Pratakshya ◽  
J. S. Nowick ◽  
A. A. Gorodetsky
Keyword(s):  
Amino Acids ◽  
Unnatural Amino Acids ◽  
Building Blocks ◽  
Solid Support ◽  
Diels Alder

The synthesis of quinoline-based unnatural amino acids and the subsequent preparation of polypeptide surrogates from these building blocks on solid support.

ChemInform Abstract: Cyclopropyl Building Blocks for Organic Synthesis. Part 162. Diels-Alder Reactions for the Construction of Cyclopropylarenes.

ChemInform ◽  
2012 ◽  
Vol 43 (39) ◽  
pp. no-no
Author(s):  
Marion Arndt ◽  
Gerhard Hilt ◽  
Alexander F. Khlebnikov ◽  
Sergei I. Kozhushkov ◽  
Armin de Meijere
Keyword(s):  
Organic Synthesis ◽  
Building Blocks ◽  
Diels Alder
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