scholarly journals Thermodynamic Hydricities of Biomimetic Organic Hydride Donors

2018 ◽  
Vol 140 (13) ◽  
pp. 4569-4579 ◽  
Author(s):  
Stefan Ilic ◽  
Usha Pandey Kadel ◽  
Yasemin Basdogan ◽  
John A. Keith ◽  
Ksenija D. Glusac
Keyword(s):  
2007 ◽  
Vol 46 (No. 23) ◽  
pp. L537-L539 ◽  
Author(s):  
Vinod Adivarahan ◽  
Qhalid Fareed ◽  
Surendra Srivastava ◽  
Thomas Katona ◽  
Mikhail Gaevski ◽  
...  

2011 ◽  
Vol 105 (2) ◽  
pp. 381-389 ◽  
Author(s):  
Yoshihide Danjo ◽  
Iori Kikuchi ◽  
Yosuke Ino ◽  
Masa-aki Ohshima ◽  
Hideki Kurokawa ◽  
...  

2018 ◽  
Vol 10 (12) ◽  
pp. 4477 ◽  
Author(s):  
Kiyotaka Tsunemi ◽  
Kikuo Yoshida ◽  
Takehiro Kihara ◽  
Tei Saburi ◽  
Kyoko Ono

This study involves a screening-level risk assessment of the impairment of human health and life related to hydrogen explosion and chemical release during the operation of a hydrogen refueling station (HRS) that uses organic hydride. First, twenty-one accident scenarios were identified involving the leakage of hydrogen, toluene and methylcyclohexane (MCH) in the HRS. Next, the leakage frequency for each scenario was estimated using a hierarchical Bayesian model. Simulations were then performed of the blast-wave pressure and heat radiation after a hydrogen leak and of atmospheric dispersion of evaporated chemicals after leaks of liquid MCH and toluene. The consequences were estimated for each scenario according to leak size using the existing probit functions and threshold values. Finally, the risk due to explosion, heat radiation, and acute toxicity was estimated by multiplying the consequence by the leakage frequency. The results show that the mortality risk of explosion and acute effect is less than 10−6 per year, which is a negligible level of concern. However, the mortality risk of heat radiation in the scenarios involving hydrogen leakage from the pipe connected to the cylinders and compressors exceeds 10−4 per year inside the HRS, thereby requiring additional steps if a more-detailed risk assessment is needed.


2013 ◽  
Vol 38 (32) ◽  
pp. 14010-14026 ◽  
Author(s):  
Faisal Alhumaidan ◽  
Dimos Tsakiris ◽  
David Cresswell ◽  
Arthur Garforth

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