scholarly journals Stereochemical Sequence Dictates Unimolecular Diblock Copolymer Assembly

2018 ◽  
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Tristan Bereau ◽  
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Navjot Singh ◽  
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Juan Zhang ◽  
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Oleksandr O. Mykhaylyk ◽  
Elizabeth R. Jones ◽  
Steven P. Armes

RAFT aqueous emulsion polymerization of hydroxybutyl methacrylate using a poly(glycerol monomethacrylate) precursor leads to diblock copolymer spheres, worms or vesicles. A pseudo-phase diagram is constructed and the vesicles are briefly evaluated as a Pickering emulsifier.


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