scholarly journals Synthesis of Enantioenriched Allylic Silanes via Nickel-Catalyzed Reductive Cross-Coupling

2017 ◽  
Vol 140 (1) ◽  
pp. 139-142 ◽  
Author(s):  
Julie L. Hofstra ◽  
Alan H. Cherney ◽  
Ciara M. Ordner ◽  
Sarah E. Reisman
Keyword(s):  
Cross Coupling ◽  
Allylic Silanes

scholarly journals Regio- and Stereoselective Allylindation of Alkynes Using InBr3 and Allylic Silanes: Synthesis, Characterization, and Application of 1,4-Dienylindiums toward Skipped Dienes

Molecules ◽  
2018 ◽  
Vol 23 (8) ◽  
pp. 1884 ◽  
Author(s):  
Yoshihiro Nishimoto ◽  
Junyi Yi ◽  
Tatsuaki Takata ◽  
Akio Baba ◽  
Makoto Yasuda
Keyword(s):  
Spectral Analysis ◽  
Cross Coupling ◽  
Synthetic Methods ◽  
Sequential Process ◽  
One Pot ◽  
Allylic Silanes

Regioselective anti-allylindation of alkynes was achieved using InBr3 and allylic silanes. Various types of alkynes and allylic silanes were applicable to the present allylindation. This sequential process used the generated 1,4-dienylindiums to establish novel synthetic methods for skipped dienes. The 1,4-dienylindiums were characterized by spectral analysis and treated with I2 to stereoselectively give 1-iodo-1,4-dienes. The Pd-catalyzed cross coupling of 1,4-dienylindium with iodobenzene successfully proceeded in a one-pot manner to afford the corresponding 1-aryl-1,4-diene.

Photoredox/Pd dual-catalytic three-component cross-coupling

2020 ◽  
Author(s):  
Logan Forshee ◽  
Kaitie Cartwright ◽  
Jon Tunge ◽  
Megan Hegarty
Keyword(s):  
Cross Coupling
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