scholarly journals Revealing the Physicochemical Basis of Organic Solid–Solid Wetting Deposition: Casimir-like Forces, Hydrophobic Collapse, and the Role of the Zeta Potential

2018 ◽  
Vol 140 (4) ◽  
pp. 1327-1336 ◽  
Author(s):  
Alexander Eberle ◽  
Thomas Markert ◽  
Frank Trixler
Vox Sanguinis ◽  
1973 ◽  
Vol 24 (3) ◽  
pp. 273-279 ◽  
Author(s):  
F. Stratton ◽  
Violet I. Rawlinson ◽  
P.K. Phillips
Keyword(s):  

2005 ◽  
pp. 3808 ◽  
Author(s):  
Seiken Nakamatsu ◽  
Shinji Toyota ◽  
William Jones ◽  
Fumio Toda

2014 ◽  
Vol 70 (a1) ◽  
pp. C669-C669
Author(s):  
Angshuman Roy Choudhury ◽  
Gurpreet Kaur ◽  
Maheswararao Karanam ◽  
Sandhya Patel

The phrase "Organic fluorine" [1] was introduced by Dunitz and Taylor in 1997 to identify the C–F bonds in organic systems. Different research groups have used the phrase to glorify or deny the influence of C–F bond in crystal lattices. Once Dunitz stated that "Organic Fluorine: Odd Man Out" and Howard et al. questioned the role of "Organic fluorine" in crystal engineering. While some researchers have refuted the role of "organic fluorine" in crystal packing; the others indicated the importance of the interactions involving the same group. A number of publications have shown the importance of "Organic fluorine" in influencing crystal packing. We have been interested in the area of weak interactions in organic solid state chemistry since 1999 [2]; especially interactions involving "Organic fluorine". The study is being conducted following a systematic approach and is still in progress. We have looked at the structures of a number if tetrahydroisoquinoline derivatives, a number of differently substituted imines, phenyleacetanilydes, benzanilides and azobenzenes [3] etc. in order to elucidate the influence of "Organic fluorine" in crystal engineering both in the presence and in the absence of strong hydrogen bonding functional groups present within the molecule. A short summary of our observations will be highlighted in the presentation.


2018 ◽  
Vol 20 (43) ◽  
pp. 27385-27393 ◽  
Author(s):  
Anu Kundu ◽  
Subramanian Karthikeyan ◽  
Yoshimitsu Sagara ◽  
Dohyun Moon ◽  
Savarimuthu Philip Anthony

Triphenylamine-imidazole molecules exhibited unprecedented light induced fluorescence switching via conformational change.


2020 ◽  
Vol 208 ◽  
pp. 239-243
Author(s):  
Yasamen R. Humudat ◽  
Saadi K. Al-Naseri

2012 ◽  
Vol 507 ◽  
pp. 27-34
Author(s):  
Xin Ming Su ◽  
Ai Ying Wu ◽  
Paula M. Vilarinho

A successful electrophoretic deposition (EPD) markedly depends on the stability of the suspension. In this study the role of Triethanolamine (TEA) as a stabilizer in EPD of thick films of TiTe3O8 is presented. TiTe3O8 powders were synthesized via a conventional solid-state-reaction method and dispersed in acetone with and without TEA. The stability of the suspensions was addressed by zeta-potential, UV light and FTIR measurements. The specific adsorption of TEA to TiTe3O8 particles results in a high zeta potential and improved stability of the suspensions, allowing the preparation of high quality TiTe3O8 thick films on Pt coated Si substrates. TiTe3O8 films sintered at 700 °C are dense and homogeneous.


2015 ◽  
Vol 72 (5) ◽  
pp. 762-769 ◽  
Author(s):  
Dong-Heui Kwak ◽  
Mi-Sug Kim

The effect of chemical coagulation and biological auto-flocculation relative to zeta potential was examined to compare flotation and sedimentation separation processes for algae harvesting. Experiments revealed that microalgae separation is related to auto-flocculation of Anabaena spp. and requires chemical coagulation for the whole period of microalgae cultivation. In addition, microalgae separation characteristics which are associated with surfactants demonstrated optimal microalgae cultivation time and separation efficiency of dissolved CO2 flotation (DCF) as an alternative to dissolved air flotation (DAF). Microalgae were significantly separated in response to anionic surfactant rather than cationic surfactant as a function of bubble size and zeta potential. DAF and DCF both showed slightly efficient flotation; however, application of anionic surfactant was required when using DCF.


Nanomaterials ◽  
2018 ◽  
Vol 8 (12) ◽  
pp. 1028 ◽  
Author(s):  
Soyeon Jeon ◽  
Jessica Clavadetscher ◽  
Dong-Keun Lee ◽  
Sunay Chankeshwara ◽  
Mark Bradley ◽  
...  

The evaluation of the role of physicochemical properties in the toxicity of nanoparticles is important for the understanding of toxicity mechanisms and for controlling the behavior of nanoparticles. The surface charge of nanoparticles is suggested as one of the key parameters which decide their biological impact. In this study, we synthesized fluorophore-conjugated polystyrene nanoparticles (F-PLNPs), with seven different types of surface functional groups that were all based on an identical core, to evaluate the role of surface charge in the cellular uptake of nanoparticles. Phagocytic differentiated THP-1 cells or non-phagocytic A549 cells were incubated with F-PLNP for 4 h, and their cellular uptake was quantified by fluorescence intensity and confocal microscopy. The amount of internalized F-PLNPs showed a good positive correlation with the zeta potential of F-PLNPs in both cell lines (Pearson’s r = 0.7021 and 0.7852 for zeta potential vs. cellular uptake in THP-1 cells and nonphagocytic A549 cells, respectively). This result implies that surface charge is the major parameter determining cellular uptake efficiency, although other factors such as aggregation/agglomeration, protein corona formation, and compositional elements can also influence the cellular uptake partly or indirectly.


Vox Sanguinis ◽  
1973 ◽  
Vol 24 (3) ◽  
pp. 273-279 ◽  
Author(s):  
F. Stratton ◽  
Violet I. Rawlinson ◽  
H. H. Gunson ◽  
P. K. Phillips
Keyword(s):  

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