Formation of 1D Infinite Chains Directed by Metal–Metal and/or π–π Stacking Interactions of Water-Soluble Platinum(II) 2,6-Bis(benzimidazol-2′-yl)pyridine Double Complex Salts

2018 ◽  
Vol 140 (2) ◽  
pp. 657-666 ◽  
Author(s):  
Victor Chun-Hei Wong ◽  
Charlotte Po ◽  
Sammual Yu-Lut Leung ◽  
Alan Kwun-Wa Chan ◽  
Siyuan Yang ◽  
...  
Keyword(s):  
Water Soluble ◽  
Stacking Interactions ◽  
Double Complex ◽  
Double Complex Salts ◽  
Π Stacking ◽  
Metal Metal ◽  
Complex Salts

Cobaloxime-Based Double Complex Salts as Efficient and Versatile Catalysts for the Light-Driven Hydrogen Evolution Reaction

2020 ◽  
Author(s):  
Elisabeth Hofmeister ◽  
Jisoo Woo ◽  
Tobias Ullrich ◽  
Lydia Petermann ◽  
Kevin Hanus ◽  
...  
Keyword(s):  
Hydrogen Evolution ◽  
Hydrogen Evolution Reaction ◽  
Systematic Study ◽  
Cobalt Complexes ◽  
Spectroscopic Studies ◽  
Double Complex ◽  
Double Complex Salts ◽  
Noble Metal Catalysts ◽  
Reduction Potentials ◽  
Complex Salts

Cobaloximes and their BF<sub>2</sub>-bridged analogues have emerged as promising non-noble metal catalysts for the photocatalytic hydrogen evolution reaction (HER). Herein we report the serendipitous discovery that double complex salts such as [Co(dmgh)<sub>2</sub>py<sub>2</sub>]<sup>+</sup>[Co(dmgBPh<sub>2</sub>)<sub>2</sub>Cl<sub>2</sub>]<sup>-</sup> can be obtained in good yields by treatment of commercially available [Co(dmgh)<sub>2</sub>pyCl] with triarylboranes. A systematic study on the use of such double complex salts and their single salts with simple counterions as photocatalysts revealed HER activities comparable or superior to existing cobaloxime catalysts and suggests ample opportunities for this compound class in catalyst/photosensitizer dyads and immobilized architectures. Preliminary electrochemical and spectroscopic studies indicate that one key advantage of these charged cobalt complexes is that the reduction potentials as well as the electrostatic interaction with charged photosensitizers can be tuned.

Synthesis of CuxNi1−x alloy nanoparticles from double complex salts and investigation of their magnetoimpedance effects

RSC Advances ◽  
2015 ◽  
Vol 5 (88) ◽  
pp. 71601-71607 ◽  
Author(s):  
Seyed Abolghasem Kahani ◽  
Mansoure Shahrokh
Keyword(s):  
Reduction Method ◽  
Chemical Reduction ◽  
Alloy Nanoparticles ◽  
Chemical Reduction Method ◽  
Double Complex ◽  
Double Complex Salts ◽  
Complex Salts

This work is a novel study of the synthesis of CuxNi1−x nanoalloy from double complex salts by chemical reduction method.

Investigation of thermal properties of double complex salts [M(NH3)5Br][AuBr4]2·nH2O, M = Rh, Ir

2011 ◽  
Vol 109 (2) ◽  
pp. 901-905
Author(s):  
E. Yu. Semitut ◽  
P. E. Plyusnin ◽  
Yu. V. Shubin ◽  
S. A. Veniaminov ◽  
S. V. Korenev
Keyword(s):  
Thermal Properties ◽  
Double Complex ◽  
Double Complex Salts ◽  
Complex Salts

Isostructurality and Thermal Properties in the Series of Double Complex Salts [M1(NH3)6][M2(C2O4)3]·3H2O (M1 = Co, Ir, M2 = Fe, Cr)

2019 ◽  
Vol 60 (7) ◽  
pp. 1062-1071 ◽  
Author(s):  
K. V. Yusenko ◽  
S. I. Pechenyuk ◽  
E. S. Vikulova ◽  
Yu. P. Semushina ◽  
I. A. Baidina ◽  
...  
Keyword(s):  
Thermal Properties ◽  
Double Complex ◽  
Double Complex Salts ◽  
Complex Salts

Double complex salts containing [Pt(NO3)6]2- anion and Rh(III) complex cations: Synthesis, structure and utilisation for preparing (Rh–Pt)/CeO2 catalysts

2020 ◽  
Vol 1211 ◽  
pp. 128108
Author(s):  
Danila Vasilchenko ◽  
Polina Topchiyan ◽  
Iraida Baidina ◽  
Ilya Korolkov ◽  
Evgeny Filatov ◽  
...  
Keyword(s):  
Double Complex ◽  
Double Complex Salts ◽  
Complex Salts

Double complex salts of Pt and Pd ammines with Zn and Ni oxalates – promising precursors of nanosized alloys

2008 ◽  
Vol 361 (1) ◽  
pp. 199-207 ◽  
Author(s):  
A.V. Zadesenets ◽  
E.Yu. Filatov ◽  
K.V. Yusenko ◽  
Yu.V. Shubin ◽  
S.V. Korenev ◽  
...  
Keyword(s):  
Double Complex ◽  
Double Complex Salts ◽  
Complex Salts
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