scholarly journals Ultrafast Solvation Dynamics and Vibrational Coherences of Halogenated Boron-Dipyrromethene Derivatives Revealed through Two-Dimensional Electronic Spectroscopy

2017 ◽  
Vol 139 (41) ◽  
pp. 14733-14742 ◽  
Author(s):  
Yumin Lee ◽  
Saptaparna Das ◽  
Roy M. Malamakal ◽  
Stephen Meloni ◽  
David M. Chenoweth ◽  
...  
2010 ◽  
Vol 24 (3-4) ◽  
pp. 393-397 ◽  
Author(s):  
K. L .M. Lewis ◽  
J. A. Myers ◽  
F. Fuller ◽  
P. F. Tekavec ◽  
J. P. Ogilvie

Two-dimensional electronic spectroscopy is a sensitive probe of solvation dynamics. Using a pump–probe geometry with a pulse shaper [Optics Express15(2007), 16681-16689;Optics Express16(2008), 17420-17428], we present temperature dependent 2D spectra of laser dyes dissolved in glass-forming solvents. At low waiting times, the system has not yet relaxed, resulting in a spectrum that is elongated along the diagonal. At longer times, the system loses its memory of the initial excitation frequency, and the 2D spectrum rounds out. As the temperature is lowered, the time scale of this relaxation grows, and the elongation persists for longer waiting times. This can be measured in the ratio of the diagonal width to the anti-diagonal width; the behavior of this ratio is representative of the frequency–frequency correlation function [Optics Letters31(2006), 3354–3356]. Near the glass transition temperature, the relaxation behavior changes. Understanding this change is important for interpreting temperature-dependent dynamics of biological systems.


2014 ◽  
Vol 140 (8) ◽  
pp. 084701 ◽  
Author(s):  
Justin R. Caram ◽  
Haibin Zheng ◽  
Peter D. Dahlberg ◽  
Brian S. Rolczynski ◽  
Graham B. Griffin ◽  
...  

2018 ◽  
Vol 207 ◽  
pp. 233-250 ◽  
Author(s):  
Javier Segarra-Martí ◽  
Vishal K. Jaiswal ◽  
Ana Julieta Pepino ◽  
Angelo Giussani ◽  
Artur Nenov ◽  
...  

A computational strategy to simulate two-dimensional electronic spectra (2DES) is introduced, which allows characterising ground state conformations of flexible nucleobase aggregates that play a crucial role in nucleic acid photochemistry.


2013 ◽  
Vol 104 (2) ◽  
pp. 653a
Author(s):  
Henry D. Wilson ◽  
Franklin D. Fuller ◽  
Charles F. Yocum ◽  
Jennifer P. Ogilvie

2013 ◽  
Vol 41 ◽  
pp. 05032 ◽  
Author(s):  
A. Halpin ◽  
P.J.M. Johnson ◽  
R.S. Murphy ◽  
V.I. Prokhorenko ◽  
R.J.D. Miller

2021 ◽  
Vol 155 (9) ◽  
pp. 094201
Author(s):  
Damianos Agathangelou ◽  
Ariba Javed ◽  
Francesco Sessa ◽  
Xavier Solinas ◽  
Manuel Joffre ◽  
...  

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