scholarly journals Metal-Free Borylation of Heteroarenes Using Ambiphilic Aminoboranes: On the Importance of Sterics in Frustrated Lewis Pair C–H Bond Activation

2017 ◽  
Vol 139 (41) ◽  
pp. 14714-14723 ◽  
Author(s):  
Julien Légaré Lavergne ◽  
Arumugam Jayaraman ◽  
Luis C. Misal Castro ◽  
Étienne Rochette ◽  
Frédéric-Georges Fontaine
Keyword(s):  
Bond Activation ◽  
Metal Free ◽  
Frustrated Lewis Pair

Metal-free photocatalytic C(sp3)–H bond activation

2021 ◽  
Author(s):  
Cristina V. Craescu ◽  
Matthew J. Schubach ◽  
Steven Huss ◽  
Elizabeth Elacqua
Keyword(s):  
Bond Activation ◽  
Metal Free

Expanding the Scope of Metal-Free Catalytic Hydrogenation through Frustrated Lewis Pair Design

2010 ◽  
Vol 122 (37) ◽  
pp. 6709-6713 ◽  
Author(s):  
Gábor Erős ◽  
Hasan Mehdi ◽  
Imre Pápai ◽  
Tibor András Rokob ◽  
Péter Király ◽  
...  
Keyword(s):  
Catalytic Hydrogenation ◽  
Metal Free ◽  
Frustrated Lewis Pair

scholarly journals Reversible O–H bond activation by an intramolecular frustrated Lewis pair

2019 ◽  
Vol 48 (9) ◽  
pp. 2896-2899 ◽  
Author(s):  
Petra Vasko ◽  
M. Ángeles Fuentes ◽  
Jamie Hicks ◽  
Simon Aldridge
Keyword(s):  
Bond Activation ◽  
Frustrated Lewis Pairs ◽  
Frustrated Lewis Pair ◽  
Lewis Pairs

The interactions of the O–H bonds in alcohols, water and phenol with dimethylxanthene-derived frustrated Lewis pairs (FLPs) have been probed.

Metal-Free Iodoperfluoroalkylation: Photocatalysis versus Frustrated Lewis Pair Catalysis

Synthesis ◽  
2020 ◽  
Vol 53 (01) ◽  
pp. 123-134
Author(s):  
Constantin Czekelius ◽  
Lucas Helmecke ◽  
Michael Spittler ◽  
Bernd M. Schmidt
Keyword(s):  
Visible Light ◽  
Visible Light Irradiation ◽  
Light Irradiation ◽  
Reaction Pathways ◽  
Frustrated Lewis Pairs ◽  
Metal Free ◽  
Comprehensive Account ◽  
Frustrated Lewis Pair ◽  
Catalytic Metal ◽  
Lewis Pairs

A comparison of two catalytic, metal-free iodoperfluoro­alkylation protocols is presented. Frustrated Lewis pairs [ t Bu3P/B(C6F5)3] or phosphines/phosphites under visible light irradiation efficiently mediate the functionalization of non-activated alkenes and alkynes. A comprehensive account of the corresponding substrate scopes as well as insights into the mechanistic details of both reaction pathways are provided.

ChemInform Abstract: Metal-Free, One-Pot Synthesis of Allylic and Benzylic Esters via Decarboxylation and C-H Bond Activation.

ChemInform ◽  
2015 ◽  
Vol 46 (24) ◽  
pp. no-no
Author(s):  
Hanjie Mo ◽  
Dingben Chen ◽  
Lingzhen Xu ◽  
Di Chen ◽  
Fuyuo Pan ◽  
...  
Keyword(s):  
Bond Activation ◽  
One Pot ◽  
Metal Free ◽  
One Pot Synthesis

Metal-Free Selective Borylation of Arenes by a Diazadiborinine via C–H/C–F Bond Activation and Dearomatization

2019 ◽  
Vol 141 (35) ◽  
pp. 13729-13733 ◽  
Author(s):  
Yuanting Su ◽  
Dinh Cao Huan Do ◽  
Yongxin Li ◽  
Rei Kinjo
Keyword(s):  
Bond Activation ◽  
Metal Free
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