scholarly journals Anisotropic Self-Assembly of Supramolecular Polymers and Plasmonic Nanoparticles at the Liquid–Liquid Interface

2017 ◽  
Vol 139 (6) ◽  
pp. 2345-2350 ◽  
Author(s):  
Joseph J. Armao ◽  
Irina Nyrkova ◽  
Gad Fuks ◽  
Artem Osypenko ◽  
Mounir Maaloum ◽  
...  
Keyword(s):  
Self Assembly ◽  
Liquid Interface ◽  
Plasmonic Nanoparticles ◽  
Supramolecular Polymers

Tuneable 2D self-assembly of plasmonic nanoparticles at liquid|liquid interfaces

Nanoscale ◽  
2016 ◽  
Vol 8 (46) ◽  
pp. 19229-19241 ◽  
Author(s):  
Leonora Velleman ◽  
Debabrata Sikdar ◽  
Vladimir A. Turek ◽  
Anthony R. Kucernak ◽  
Steve J. Roser ◽  
...  
Keyword(s):  
Small Angle ◽  
Self Assembly ◽  
Liquid Interface ◽  
Plasmonic Nanoparticles ◽  
Liquid Interfaces ◽  
X Ray Diffraction ◽  
Optical Reflectance ◽  
X Ray ◽  
Nanoparticle Films ◽  
Plasmon Ruler

Validation of the plasmon ruler through small angle X-ray diffraction and optical reflectance of ordered nanoparticle films at the liquid–liquid interface.

Tweaking a BODIPY Spherical Self‐Assembly to 2D Supramolecular Polymers Facilitates Excited State Cascade Energy Transfer

2021 ◽  
Author(s):  
Gourab Das ◽  
Sandeep Cherumukkil ◽  
Akhil Padmakumar ◽  
Vijay B. Banakar ◽  
Vakayil K. Praveen ◽  
...  
Keyword(s):  
Energy Transfer ◽  
Excited State ◽  
Self Assembly ◽  
Supramolecular Polymers ◽  
Cascade Energy

Tweaking a BODIPY Spherical Self‐Assembly to 2D Supramolecular Polymers Facilitates Excited State Cascade Energy Transfer

2021 ◽  
Author(s):  
Gourab Das ◽  
Sandeep Cherumukkil ◽  
Akhil Padmakumar ◽  
Vijay B. Banakar ◽  
Vakayil K. Praveen ◽  
...  
Keyword(s):  
Energy Transfer ◽  
Excited State ◽  
Self Assembly ◽  
Supramolecular Polymers ◽  
Cascade Energy

Star-like supramolecular polymers fabricated by a Keplerate cluster with cationic terminated polymers and their self-assembly into vesicles

2012 ◽  
Vol 48 (56) ◽  
pp. 7067 ◽  
Author(s):  
Qian Zhang ◽  
Lipeng He ◽  
Hui Wang ◽  
Cheng Zhang ◽  
Weisheng Liu ◽  
...  
Keyword(s):  
Self Assembly ◽  
Supramolecular Polymers

scholarly journals Living supramolecular polymerization of fluorinated cyclohexanes

2021 ◽  
Vol 12 (1) ◽  
Author(s):  
Oleksandr Shyshov ◽  
Shyamkumar Vadakket Haridas ◽  
Luca Pesce ◽  
Haoyuan Qi ◽  
Andrea Gardin ◽  
...  
Keyword(s):  
Dipole Moment ◽  
Self Assembly ◽  
Materials Science ◽  
Helical Structure ◽  
The Self ◽  
Supramolecular Polymers ◽  
Aliphatic Compound ◽  
Double Helical Structure ◽  
Key Driver ◽  
Supramolecular Polymerization

AbstractThe development of powerful methods for living covalent polymerization has been a key driver of progress in organic materials science. While there have been remarkable reports on living supramolecular polymerization recently, the scope of monomers is still narrow and a simple solution to the problem is elusive. Here we report a minimalistic molecular platform for living supramolecular polymerization that is based on the unique structure of all-cis 1,2,3,4,5,6-hexafluorocyclohexane, the most polar aliphatic compound reported to date. We use this large dipole moment (6.2 Debye) not only to thermodynamically drive the self-assembly of supramolecular polymers, but also to generate kinetically trapped monomeric states. Upon addition of well-defined seeds, we observed that the dormant monomers engage in a kinetically controlled supramolecular polymerization. The obtained nanofibers have an unusual double helical structure and their length can be controlled by the ratio between seeds and monomers. The successful preparation of supramolecular block copolymers demonstrates the versatility of the approach.

scholarly journals Controlling the length of porphyrin supramolecular polymers via coupled equilibria and dilution-induced supramolecular polymerization

2022 ◽  
Vol 13 (1) ◽  
Author(s):  
Elisabeth Weyandt ◽  
Luigi Leanza ◽  
Riccardo Capelli ◽  
Giovanni M. Pavan ◽  
Ghislaine Vantomme ◽  
...  
Keyword(s):  
Complex Systems ◽  
Self Assembly ◽  
Chiral Discrimination ◽  
Coarse Grained ◽  
Supramolecular Polymers ◽  
Supramolecular System ◽  
Precise Control ◽  
Aggregate Morphology ◽  
The Individual ◽  
Supramolecular Polymerization

AbstractMulti-component systems often display convoluted behavior, pathway complexity and coupled equilibria. In recent years, several ways to control complex systems by manipulating the subtle balances of interaction energies between the individual components have been explored and thereby shifting the equilibrium between different aggregate states. Here we show the enantioselective chain-capping and dilution-induced supramolecular polymerization with a Zn2+-porphyrin-based supramolecular system when going from long, highly cooperative supramolecular polymers to short, disordered aggregates by adding a monotopic Mn3+-porphyrin monomer. When mixing the zinc and manganese centered monomers, the Mn3+-porphyrins act as chain-cappers for Zn2+-porphyrin supramolecular polymers, effectively hindering growth of the copolymer and reducing the length. Upon dilution, the interaction between chain-capper and monomers weakens as the equilibria shift and long supramolecular polymers form again. This dynamic modulation of aggregate morphology and length is achieved through enantioselectivity in the aggregation pathways and concentration-sensitive equilibria. All-atom and coarse-grained molecular simulations provide further insights into the mixing of the species and their exchange dynamics. Our combined experimental and theoretical approach allows for precise control of molecular self-assembly and chiral discrimination in complex systems.

scholarly journals Aqueous interfacial gels assembled from small molecule supramolecular polymers

2017 ◽  
Vol 8 (2) ◽  
pp. 1350-1355 ◽  
Author(s):  
Alexander S. Groombridge ◽  
Aniello Palma ◽  
Richard M. Parker ◽  
Chris Abell ◽  
Oren A. Scherman
Keyword(s):  
Small Molecules ◽  
Small Molecule ◽  
Self Assembly ◽  
Hyperbranched Polymer ◽  
Soft Matter ◽  
Supramolecular Polymers ◽  
Supramolecular Network ◽  
Self Healing ◽  
Liquid Interfaces ◽  
Stimuli Responsive

The successful self-assembly of a stimuli-responsive aqueous supramolecular hyperbranched polymer from small molecules and the macrocyclic host cucurbit[8]uril (CB[8]) is reported. This self-healing supramolecular network can act as a soft matter barrier at liquid–liquid interfaces.

Dynamically resolved self-assembly of S-layer proteins on solid surfaces

2018 ◽  
Vol 54 (73) ◽  
pp. 10264-10267 ◽  
Author(s):  
Bart Stel ◽  
Fernando Cometto ◽  
Behzad Rad ◽  
James J. De Yoreo ◽  
Magalí Lingenfelder
Keyword(s):  
Self Assembly ◽  
Spatial Scales ◽  
Liquid Interface ◽  
Solid Surfaces ◽  
Solid Liquid Interface ◽  
Solid Liquid

Kinetic pathway in S-layer self-assembly at the solid–liquid interface across time (second to hours) and spatial scales (nm to microns).

Crown ether‐based supramolecular polymers: from synthesis to self‐assembly

2021 ◽  
pp. 2100775
Author(s):  
Zhaozhao Duan ◽  
Fenfen Xu ◽  
Xiaohui Huang ◽  
Yongchao Qian ◽  
Hui Li ◽  
...  
Keyword(s):  
Crown Ether ◽  
Self Assembly ◽  
Supramolecular Polymers
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