scholarly journals Catalytic, Enantioselective Addition of Alkyl Radicals to Alkenes via Visible-Light-Activated Photoredox Catalysis with a Chiral Rhodium Complex

2016 ◽  
Vol 138 (22) ◽  
pp. 6936-6939 ◽  
Author(s):  
Haohua Huo ◽  
Klaus Harms ◽  
Eric Meggers
Keyword(s):  
Visible Light ◽  
Rhodium Complex ◽  
Photoredox Catalysis ◽  
Alkyl Radicals ◽  
Enantioselective Addition

scholarly journals Carbonylation of Alkyl Radicals Derived from Organosilicates through Visible‐Light Photoredox Catalysis

2019 ◽  
Vol 58 (6) ◽  
pp. 1789-1793 ◽  
Author(s):  
Alex Cartier ◽  
Etienne Levernier ◽  
Vincent Corcé ◽  
Takahide Fukuyama ◽  
Anne‐Lise Dhimane ◽  
...  
Keyword(s):  
Visible Light ◽  
Photoredox Catalysis ◽  
Alkyl Radicals

scholarly journals Carbonylation of Alkyl Radicals Derived from Organosilicates through Visible‐Light Photoredox Catalysis

2019 ◽  
Vol 131 (6) ◽  
pp. 1803-1807 ◽  
Author(s):  
Alex Cartier ◽  
Etienne Levernier ◽  
Vincent Corcé ◽  
Takahide Fukuyama ◽  
Anne‐Lise Dhimane ◽  
...  
Keyword(s):  
Visible Light ◽  
Photoredox Catalysis ◽  
Alkyl Radicals

A Desulfurative Strategy for the Generation of Alkyl Radicals Enabled by Visible‐Light Photoredox Catalysis

2018 ◽  
Vol 57 (22) ◽  
pp. 6667-6671 ◽  
Author(s):  
Fei Xue ◽  
Falu Wang ◽  
Jiazhen Liu ◽  
Jiamei Di ◽  
Qi Liao ◽  
...  
Keyword(s):  
Visible Light ◽  
Photoredox Catalysis ◽  
Alkyl Radicals

A Desulfurative Strategy for the Generation of Alkyl Radicals Enabled by Visible‐Light Photoredox Catalysis

2018 ◽  
Vol 130 (22) ◽  
pp. 6777-6781 ◽  
Author(s):  
Fei Xue ◽  
Falu Wang ◽  
Jiazhen Liu ◽  
Jiamei Di ◽  
Qi Liao ◽  
...  
Keyword(s):  
Visible Light ◽  
Photoredox Catalysis ◽  
Alkyl Radicals

Regioselective C3-H Trifluoromethylation of 2H-Indazole Under Transition-Metal-Free Photoredox Catalysis

2019 ◽  
Author(s):  
Arumugavel Murugan ◽  
Venkata Nagarjuna Babu ◽  
Nagaraj Sabarinathan ◽  
Sharada Duddu. S
Keyword(s):  
Transition Metal ◽  
Visible Light ◽  
Practical Approach ◽  
Hypervalent Iodine ◽  
Radical Mechanism ◽  
Photoredox Catalysis ◽  
Metal Free

Here we report a visible-light-promoted metal-free regioselective C3-H trifluoromehtylation reaction that proceeds via radical mechanism and which supported by control experiments. The combination of photoredox catalysis and hypervalent iodine reagent provides a practical approach for the present trifluoromethylation reaction and synthesis of a library of trifluoromethylated indazoles.

Visible-Light Photosensitized Aryl and Alkyl Decarboxylative Carbon-Heteroatom and Carbon-Carbon Bond Formations

2019 ◽  
Author(s):  
Tuhin Patra ◽  
Satobhisha Mukherjee ◽  
Jiajia Ma ◽  
Felix Strieth-Kalthoff ◽  
Frank Glorius
Keyword(s):  
Energy Transfer ◽  
Visible Light ◽  
Alkyl Radical ◽  
General Strategy ◽  
Alkyl Radicals ◽  
Bond Forming ◽  
Radical Trapping ◽  
Carbon Carbon Bond ◽  
Radical Generation ◽  
Trapping Agent

<sub>A general strategy to access both aryl and alkyl radicals by photosensitized decarboxylation of the corresponding carboxylic acids esters has been developed. An energy transfer mediated homolysis of unsymmetrical sigma-bonds for a concerted fragmentation/decarboxylation process is involved. As a result, an independent aryl/alkyl radical generation step enables a series of key C-X and C-C bond forming reactions by simply changing the radical trapping agent.</sub>

Enantioselective Radical Functionalization of Imines and Iminium Intermediates via Visible Light Photoredox Catalysis

Synthesis ◽  
2020 ◽  
Author(s):  
Jia-Jia Zhao ◽  
Hong-Hao Zhang ◽  
Shouyun Yu
Keyword(s):  
Visible Light ◽  
Asymmetric Synthesis ◽  
Carbonyl Compounds ◽  
Asymmetric Reduction ◽  
Chemical Transformations ◽  
Photoredox Catalysis ◽  
Radical Coupling ◽  
Mild Conditions ◽  
Iminium Ions ◽  
Radical Functionalization

Visible light photoredox catalysis has recently emerged as a powerful tool for the development of new and valuable chemical transformations under mild conditions. Visible-light promoted enantioselective radical transformations of imines and iminium intermediates provide new opportunities for the asymmetric synthesis of amines and asymmetric β-functionalization of unsaturated carbonyl compounds. In this review, the advance in the catalytic asymmetric radical functionalization of imines, as well as iminium intermediates, are summarized. 1 Introduction 2 The enantioselective radical functionalization of imines 2.1 Asymmetric reduction 2.2 Asymmetric cyclization 2.3 Asymmetric addition 2.4 Asymmetric radical coupling 3 The enantioselective radical functionalization of iminium ions 3.1 Asymmetric radical alkylation 3.2 Asymmetric radical acylation 4 Conclusion

Intermolecular Aminotrifluoromethylation of Alkenes by Visible-Light-Driven Photoredox Catalysis

2013 ◽  
Vol 15 (9) ◽  
pp. 2136-2139 ◽  
Author(s):  
Yusuke Yasu ◽  
Takashi Koike ◽  
Munetaka Akita
Keyword(s):  
Visible Light ◽  
Photoredox Catalysis ◽  
Visible Light Driven
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