Photoexcited Surface Frustrated Lewis Pairs for Heterogeneous Photocatalytic CO2 Reduction

2016 ◽  
Vol 138 (4) ◽  
pp. 1206-1214 ◽  
Author(s):  
Kulbir Kaur Ghuman ◽  
Laura B. Hoch ◽  
Paul Szymanski ◽  
Joel Y. Y. Loh ◽  
Nazir P. Kherani ◽  
...  
Keyword(s):  
Co2 Reduction ◽  
Frustrated Lewis Pairs ◽  
Lewis Pairs

scholarly journals Crystal facet-dependent frustrated Lewis pairs on dual-metal hydroxide for photocatalytic CO2 reduction

2021 ◽  
pp. 120748
Author(s):  
Weining Zhang ◽  
Zhenhua Yang ◽  
Hailian Wang ◽  
Lei Lu ◽  
Depei Liu ◽  
...  
Keyword(s):  
Co2 Reduction ◽  
Metal Hydroxide ◽  
Frustrated Lewis Pairs ◽  
Crystal Facet ◽  
Dual Metal ◽  
Lewis Pairs

Metadynamics-Biased ab Initio Molecular Dynamics Study of Heterogeneous CO2 Reduction via Surface Frustrated Lewis Pairs

ACS Catalysis ◽  
2016 ◽  
Vol 6 (10) ◽  
pp. 7109-7117 ◽  
Author(s):  
Mireille Ghoussoub ◽  
Shwetank Yadav ◽  
Kulbir Kaur Ghuman ◽  
Geoffrey A. Ozin ◽  
Chandra Veer Singh
Keyword(s):  
Molecular Dynamics ◽  
Ab Initio ◽  
Co2 Reduction ◽  
Ab Initio Molecular Dynamics ◽  
Frustrated Lewis Pairs ◽  
Lewis Pairs

Construction of Frustrated Lewis Pairs on TiO2-x Derived from Perovskite for Enhanced Photocatalytic CO2 Reduction

2021 ◽  
pp. 131554
Author(s):  
Changchao Jia ◽  
Xiaonan Kan ◽  
Xia Zhang ◽  
Gang Lin ◽  
Wengang Liu ◽  
...  
Keyword(s):  
Co2 Reduction ◽  
Frustrated Lewis Pairs ◽  
Lewis Pairs

Bis(perchlorocatecholato)silane and Heteroleptic Bidonors: Hidden Frustrated Lewis Pairs by Ring Strain

2021 ◽  
Author(s):  
Deborah Hartmann ◽  
Sven Braner ◽  
Lutz Greb
Keyword(s):  
Ammonia Borane ◽  
Frustrated Lewis Pairs ◽  
Ring Strain ◽  
Frustrated Lewis Pair ◽  
Lewis Pairs

Bis(perchlorocatecholato)silane and bidentate N,N- or N,P-heteroleptic donors form hexacoordinated complexes. Depending on the ring strain and hemilability in the adducts, Frustrated Lewis pair reactivity with aldehydes and catalytic ammonia borane...

scholarly journals Supramolecular Systems Containing B–N Frustrated Lewis Pairs of Tris(pentafluorophenyl)borane and Triphenylamine Derivatives

2021 ◽  
Vol 03 (02) ◽  
pp. 174-183
Author(s):  
P. Chidchob ◽  
S. A. H. Jansen ◽  
S. C. J. Meskers ◽  
E. Weyandt ◽  
N. P. van Leest ◽  
...  
Keyword(s):  
Materials Science ◽  
Supramolecular Polymers ◽  
Frustrated Lewis Pairs ◽  
Paramagnetic Resonance ◽  
Donor And Acceptor ◽  
Donor Acceptor ◽  
Noncovalent Polymers ◽  
Electron Paramagnetic ◽  
Supramolecular Polymerization ◽  
Lewis Pairs

The introduction of a chemical additive to supramolecular polymers holds high potential in the development of new structures and functions. In this regard, various donor- and acceptor-based molecules have been applied in the design of these noncovalent polymers. However, the incorporation of boron–nitrogen frustrated Lewis pairs in such architectures is still rare despite their many intriguing properties in catalysis and materials science. The limited choices of suitable boron derivatives represent one of the main limitations for the advancement in this direction. Here, we examine the use of the commercially available tris(pentafluorophenyl)borane with various triphenylamine derivatives to create supramolecular B–N charge transfer systems. Our results highlight the importance of a proper balance between the donor/acceptor strength and the driving force for supramolecular polymerization to achieve stable, long-range ordered B–N systems. Detailed analyses using electron paramagnetic resonance and optical spectroscopy suggest that tris(pentafluorophenyl)borane displays complex behavior with the amide-based triphenylamine supramolecular polymers and may interact in dimers or larger chiral aggregates, depending on the specific structure of the triphenylamines.

Aromaticity can enhance the reactivity of P-donor/borole frustrated Lewis pairs

2019 ◽  
Vol 55 (5) ◽  
pp. 675-678 ◽  
Author(s):  
Jorge Juan Cabrera-Trujillo ◽  
Israel Fernández
Keyword(s):  
Frustrated Lewis Pairs ◽  
Key Factor ◽  
Novel Concept ◽  
Lewis Pairs

Herein we introduce a novel concept in FLP chemistry: aromaticity as the key factor enhancing the reactivity of FLPs.

Ring-opening of cyclopropanes by “frustrated Lewis pairs”

2010 ◽  
Vol 46 (47) ◽  
pp. 8947 ◽  
Author(s):  
Jason G. M. Morton ◽  
Meghan A. Dureen ◽  
Douglas W. Stephan
Keyword(s):  
Ring Opening ◽  
Frustrated Lewis Pairs ◽  
Lewis Pairs
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