scholarly journals Reverse Electron Transfer Completes the Catalytic Cycle in a 2,3,5-Trifluorotyrosine-Substituted Ribonucleotide Reductase

2015 ◽  
Vol 137 (45) ◽  
pp. 14387-14395 ◽  
Author(s):  
Kanchana R. Ravichandran ◽  
Ellen C. Minnihan ◽  
Yifeng Wei ◽  
Daniel G. Nocera ◽  
JoAnne Stubbe
Keyword(s):  
Electron Transfer ◽  
Ribonucleotide Reductase ◽  
Catalytic Cycle ◽  
Reverse Electron Transfer

Synthesis of diaryldifluoromethanes by Pd-catalyzed difluoroalkylation of arylboronic acids

2015 ◽  
Vol 2 (1) ◽  
pp. 38-41 ◽  
Author(s):  
Ji-Wei Gu ◽  
Wen-Hao Guo ◽  
Xingang Zhang
Keyword(s):  
Electron Transfer ◽  
Catalytic Cycle ◽  
Single Electron ◽  
Single Electron Transfer ◽  
Mechanistic Studies ◽  
Arylboronic Acids

The first example of Pd-catalyzed aryldifluoromethylation of arylboronic acids with readily available aryldifluoromethyl bromides has been described. Preliminary mechanistic studies revealed that a Pd(0)Ln-initiated single electron transfer (SET) pathway is involved in the catalytic cycle.

Proton-Coupled Electron Transfer in the Catalytic Cycle ofAlcaligenes xylosoxidansCopper-Dependent Nitrite Reductase

Biochemistry ◽  
2011 ◽  
Vol 50 (19) ◽  
pp. 4121-4131 ◽  
Author(s):  
Nicole G. H. Leferink ◽  
Cong Han ◽  
Svetlana V. Antonyuk ◽  
Derren J. Heyes ◽  
Stephen E. J. Rigby ◽  
...  
Keyword(s):  
Electron Transfer ◽  
Nitrite Reductase ◽  
Catalytic Cycle ◽  
Proton Coupled Electron Transfer

scholarly journals Diffusion, spin and reaction control in geminate reverse electron transfer

2001 ◽  
Vol 3 (2) ◽  
pp. 198-203 ◽  
Author(s):  
A. I. Burnshtein ◽  
E. Krissinel ◽  
U. E. Steiner
Keyword(s):  
Electron Transfer ◽  
Reverse Electron Transfer
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