Cyclic Ether Synthesis via Palladium-Catalyzed Directed Dehydrogenative Annulation at Unactivated Terminal Positions

2015 ◽  
Vol 137 (36) ◽  
pp. 11586-11589 ◽  
Author(s):  
Samuel J. Thompson ◽  
Danny Q. Thach ◽  
Guangbin Dong
Keyword(s):  
Cyclic Ether ◽  
Palladium Catalyzed ◽  
Ether Synthesis

Efficient Alkyl Ether Synthesis via Palladium-Catalyzed, Picolinamide-Directed Alkoxylation of Unactivated C(sp3)–H and C(sp2)–H Bonds at Remote Positions

2012 ◽  
Vol 134 (17) ◽  
pp. 7313-7316 ◽  
Author(s):  
Shu-Yu Zhang ◽  
Gang He ◽  
Yingsheng Zhao ◽  
Kiwan Wright ◽  
William A. Nack ◽  
...  
Keyword(s):  
Alkyl Ether ◽  
Palladium Catalyzed ◽  
Ether Synthesis

Cyclic ether synthesis from diols using trimethyl phosphate

2017 ◽  
Vol 53 (35) ◽  
pp. 4787-4790 ◽  
Author(s):  
Shota Asai ◽  
Maho Kato ◽  
Yasunari Monguchi ◽  
Hironao Sajiki ◽  
Yoshinari Sawama
Keyword(s):  
Room Temperature ◽  
Cyclic Ether ◽  
Cyclic Ethers ◽  
Trimethyl Phosphate ◽  
Ether Synthesis

Cyclic ethers are simply synthesized from diols by using trimethyl phosphate at room temperature.

scholarly journals A New Variant of Fused Cyclic Ether Synthesis Based on Ireland-Claisen Rearrangement and RCM

2013 ◽  
Vol 8 (7) ◽  
pp. 1934578X1300800
Author(s):  
Daisuke Domon ◽  
Kenshu Fujiwara ◽  
Natsumi Kawamura ◽  
Ryo Katoono ◽  
Hidetoshi Kawai ◽  
...  
Keyword(s):  
Olefin Metathesis ◽  
Claisen Rearrangement ◽  
Cyclic Ether ◽  
Reaction Sequence ◽  
New Variant ◽  
Ether Synthesis

A new variant of fused cyclic ether synthesis based on Ireland-Claisen rearrangement and ring-closing olefin metathesis (RCM) was developed. The Ireland-Claisen rearrangement and ring-closing olefin metathesis (RCM) was developed. The Ireland-Claisen rearrangement of a ( Z)-3-alkoxyprop-2-en-1-yl glycolate ester having a cyclic ether on the oxygen at C3 of the ( Z)-prop-2-en-1-yl group stereoselectively produced an anti-α,β-dialkoxyester which was successfully transformed to a fused bicyclic ether via a reaction sequence including RCM.

Cyclic ether synthesis: sulfenyletherification with benzenesulfenyl chloride/N, N-diisopropylethylamine and sulfenate ester cycloadditions

1987 ◽  
Vol 65 (8) ◽  
pp. 1833-1837 ◽  
Author(s):  
Sudersan M. Tuladhar ◽  
Alex G. Fallis
Keyword(s):  
Cyclic Ether ◽  
Cyclic Ethers ◽  
Nucleophilic Displacement ◽  
Ether Synthesis ◽  
Special Case ◽  
General Method ◽  
Episulfonium Ion

A general method for the formation of the cyclic ethers 9, 10, 13, 14, 16, and 28 and the lactone 30 is described. The procedure employs benzenesulfenyl chloride prepared insitu in acetonitrile and N,N-diisopropylethylamine to generate a thiiranium (episulfonium) ion intermediate from which the cyclic products arise by internal nucleophilic displacement. In the special case of the norbornene alcohols 1 and 2 the oxetanes 5 and 6 are formed by intramolecular sulfenate ester cycloaddition.

Palladium Catalyzed Aryl Enol Ether Synthesis from Vinyl Triflates.

ChemInform ◽  
2003 ◽  
Vol 34 (51) ◽  
Author(s):  
Michael C. Willis ◽  
Dawn Taylor ◽  
Adam T. Gillmore
Keyword(s):  
Enol Ether ◽  
Palladium Catalyzed ◽  
Ether Synthesis ◽  
Vinyl Triflates

ChemInform Abstract: Diazo Phosphonates in Cyclic Ether Synthesis. Use of the Intramolecular Wadsworth-Emmons Reaction.

ChemInform ◽  
2010 ◽  
Vol 23 (29) ◽  
pp. no-no
Author(s):  
C. J. MOODY ◽  
E.-R. H. B. SIE ◽  
J. J. KULAGOWSKI
Keyword(s):  
Cyclic Ether ◽  
Ether Synthesis

Visible-light-induced aerobic epoxidation in cyclic ether: Synthesis of spiroepoxyoxindole derivatives

2020 ◽  
Vol 61 (10) ◽  
pp. 151578 ◽  
Author(s):  
Kaixiu Luo ◽  
Xianglin Yu ◽  
Peng Chen ◽  
Kun He ◽  
Jun Lin ◽  
...  
Keyword(s):  
Visible Light ◽  
Cyclic Ether ◽  
Ether Synthesis
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