scholarly journals Outer-Sphere Electrophilic Fluorination of Organometallic Complexes

2015 ◽  
Vol 137 (33) ◽  
pp. 10753-10759 ◽  
Author(s):  
Lucy M. Milner ◽  
Natalie E. Pridmore ◽  
Adrian C. Whitwood ◽  
Jason M. Lynam ◽  
John M. Slattery
Keyword(s):  
Outer Sphere ◽  
Organometallic Complexes ◽  
Electrophilic Fluorination

scholarly journals Access to novel fluorovinylidene ligands via exploitation of outer-sphere electrophilic fluorination: new insights into C–F bond formation and activation

2016 ◽  
Vol 45 (4) ◽  
pp. 1717-1726 ◽  
Author(s):  
Lucy M. Milner ◽  
Lewis M. Hall ◽  
Natalie E. Pridmore ◽  
Matthew K. Skeats ◽  
Adrian C. Whitwood ◽  
...  
Keyword(s):  
Bond Formation ◽  
Outer Sphere ◽  
Electrophilic Fluorination ◽  
First Time

Metal fluorovinylidene complexes have been synthesised for the first time by direct electrophilic fluorination of metal alkynyls.

Finite difference code for velocity and surface traction of a Fluid between Two Eccentric Spheres

2015 ◽  
Vol 11 (1) ◽  
pp. 2960-2971
Author(s):  
M.Abdel Wahab
Keyword(s):  
Velocity Field ◽  
Angular Velocity ◽  
Finite Difference ◽  
Numerical Study ◽  
Outer Sphere ◽  
Equation Of Motion ◽  
Annular Region ◽  
Surface Traction ◽  
Angular Velocities ◽  
Axis Passing

The Numerical study of the flow of a fluid in the annular region between two eccentric sphere susing PHP Code isinvestigated. This flow is created by considering the inner sphere to rotate with angular velocity 1  and the outer sphererotate with angular velocity 2  about the axis passing through their centers, the z-axis, using the three dimensionalBispherical coordinates (, ,) .The velocity field of fluid is determined by solving equation of motion using PHP Codeat different cases of angular velocities of inner and outer sphere. Also Finite difference code is used to calculate surfacetractions at outer sphere.

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